Synthesis,Magnetism and Antibacterial Activity of Binuclear Copper(Ⅱ)and Cobalt(Ⅱ)Complexes

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (3): 60-64.

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Synthesis,Magnetism and Antibacterial Activity of Binuclear Copper(Ⅱ)and Cobalt(Ⅱ)Complexes

Yan Cuiwei¹, LiYantuan², Liao Daizheng³

1. Department of Biology, Qufu Normal University, Qufu;
2. Department of Chemistry, Qufu Normal University, Qufu 273165;
3. Department of Chemistry, Nankai University, Tianjin

Received:1995-10-06 Revised:1995-12-18 Published:1996-06-10 Online:1996-06-10

Abstract

Abstract: Four new binuclear complexes,[Cu₂(IPHTA)(phen)₄](ClO₄)₂(1), [Cu₂(IPHTA)(tmen)₄](ClO₄)₂·H₂O(2),[Co₂(IPHTA)(phen)₄](ClO₄)₂(3)and [Co₂(IPHTA)(tmen)₄](ClO₄)₂(4)(IPHTA,phen and tmen denote isophthalato dianion; 1,10-phenanthroline and N,N,N′,N′-tetramethylethlenediamine respectively)were synthesized and characterized by elemental analysis,IR,electronic spectra,conductivity and variable temperature magnetic susceptibility measurements.Based on the Heisenberg model, the exchange integral,J,was found to be 2.30 cm^-1for(1),3.82 cm^-1for(2),8.09 cm^-1 for(3)and 8.20 cm^-1for(4),indicating that a weak ferromagnetic spin exchange interac-tion occurs between the two metal ions.The biological activities of the complexes were also tested.

Key words: μ-isophthalate, binuclear complex, long-range magnetic interaction, antibacterial activity

Yan Cuiwei, LiYantuan, Liao Daizheng. Synthesis,Magnetism and Antibacterial Activity of Binuclear Copper(Ⅱ)and Cobalt(Ⅱ)Complexes[J]. Chinese Journal of Applied Chemistry, 1996, 0(3): 60-64.

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Synthesis,Magnetism and Antibacterial Activity of Binuclear Copper(Ⅱ)and Cobalt(Ⅱ)Complexes

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