Synthesis and Flame Retardancy for Polyvinyl Chloride of Organoantimony Compounds

Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (5): 76-78.

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Synthesis and Flame Retardancy for Polyvinyl Chloride of Organoantimony Compounds

Huang Kelong, Pan Chunyue, Tan Yougan, Liu Jian'an

Department of Chemistry, Central-South University fo Technology, Changsha 410083

Received:1995-02-16 Revised:1995-04-25 Published:1995-10-10 Online:1995-10-10

Abstract

Abstract: Organoantimony compounds of the formula ph₃SbX₂,where X=Cl,Br and pen-tachlorophenoxy,have been prepared from the reaction of triphenylantimony with CuCl₂,bromine and pentachlorophenol respectively.The compounds were characterized by elemen-tal analysis,melting point determination, infrared spectra and thermal behavior.The ther-mal decomposition mechanism was studied in air by differential scanning calorimetry,The flame retardancy of the compounds in polyvinyl chloride (PVC) was determined,which indi-cated that these compounds had high flame resisting activities for PVC at low additive levels.

Key words: organoantimony compound, flame retardancy, polyvinyl chloride, synthesis

Huang Kelong, Pan Chunyue, Tan Yougan, Liu Jian'an. Synthesis and Flame Retardancy for Polyvinyl Chloride of Organoantimony Compounds[J]. Chinese Journal of Applied Chemistry, 1995, 0(5): 76-78.

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Synthesis and Flame Retardancy for Polyvinyl Chloride of Organoantimony Compounds

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