Laser Stimulated Oxidative Coupling of Ethanol

Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (3): 18-22.

• Full Papers • Previous Articles Next Articles

Laser Stimulated Oxidative Coupling of Ethanol

Kang Qinghua, Zhong Shunhe

Department of Chemical Engineering, Tianjin University, Tianjin 300072

Received:1994-10-17 Revised:1994-12-31 Published:1995-06-10 Online:1995-06-10

Abstract

Abstract: The oxidative coupiing of ethanol stimulated by CO₂ laser on the surface of Cu₂(PO₄)(OH) and Pb₃(PO₄)₂ has been studied using XRD and IR techniques.The resultsshowed that the distribution of reaction products depends strongly on the chemisorptiontypes of ethanol:1,4-butanediol was formed via the methyl-adsorbed ethanol molecules,while the hydroxyl-adsorbed one gave to ethene.The vibrational structures of the surface ofsolid meterials are the basic factor affecting the efficiency of laser photon eiiergy, The higherefficiency of laser photon energy in the case of libethenite appeared due to the greater differ-ence in frequecies between p=O and O-Cu-O bonds.

Key words: ethanol, oxidative coupling, libethenite, lead phosphate, laser stimulated surfacereaction

Kang Qinghua, Zhong Shunhe. Laser Stimulated Oxidative Coupling of Ethanol[J]. Chinese Journal of Applied Chemistry, 1995, 0(3): 18-22.

[1]	Dan ZHANG, Run-Mei SHANG, Zhen-Tao ZHAO, Jun-Hua LI, Jin-Juan XING. Selective Oxidation of Methanol to Dimethoxymethane over V/Ce⁃Al₂O₃ Catalysts [J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1429-1436.
[2]	Xue-Ting WU, Yang YU, Shu-Yan SONG, Hong-Jie ZHANG. Artificial Carbon Sequestration Technology—Research Progress on the Catalysts for Thermal Catalytic Reduction of CO₂ [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 599-615.
[3]	Li-Zhi SUN, Hao LYU, Xiao-Wen MIN, Ben LIU. Mesoporous Palladium⁃Boron Alloy Nanocatalysts： Synthesis and Performance in Methanol Oxidation Electrocatalysis [J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 673-684.
[4]	QIAO Zong-Wen, CHEN Tao. Properties of Pyrenesulfonic Type Sulfonated Polysulfone Cation Exchange Membrane with High Performance Long Side Chain [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 668-674.
[5]	GAO Jia, SONG Fujiao, CHENG Wenqiang, GE Yan, XU Qi. Catalytic Performance of Pd-Cu/ZrO₂ Catalyst for Hydrogenation of Carbon Dioxide to Methanol [J]. Chinese Journal of Applied Chemistry, 2020, 37(2): 160-167.
[6]	HU Xueyi, LUO Minmin, FANG Yun, LI Junguo, SUN Yang, LI Huashan. A Comparative Study on the Formation of Nitrosamines of Ethanolamines [J]. Chinese Journal of Applied Chemistry, 2019, 36(9): 1061-1068.
[7]	HU Xueyi, LUO Minmin, FANG Yun, LI Junguo, SUN Yang, LI Huashan. A Comparative Study on the Formation of Nitrosamines of Ethanolamines [J]. Chinese Journal of Applied Chemistry, 2019, 36(9): 0-.
[8]	LIU Zongzhang,ZHANG Tong,XU Yuchao,JIANG　Haoxi,ZHANG　Minhua. Preparation of MgO/SBA-15 Catalyst and Its Catalytic Performance for the Synthesis of 1,3-Butadiene from Ethanol [J]. Chinese Journal of Applied Chemistry, 2019, 36(2): 176-181.
[9]	DENG Guangrong, LIANG Liang, LI Chenyang, LIU Changpeng, GE Junjie, XING Wei. Analysis of Methanol Transport and Concentration Controlling Strategy in Direct Methanol Fuel Cell [J]. Chinese Journal of Applied Chemistry, 2019, 36(10): 1211-1220.
[10]	SUN Mojie, LÜ Tao, XU Weilin. Microfluidic Synthesis of High-activity PtRu/C Catalyst for Methanol Electro-oxidation [J]. Chinese Journal of Applied Chemistry, 2018, 35(5): 564-573.
[11]	SUN Mojie, LÜ Tao, XU Weilin. Microfluidic Synthesis of High-activity PtRu/C Catalyst for Methanol Electro-oxidation [J]. Chinese Journal of Applied Chemistry, 2018, 35(5): 0-0.
[12]	ZHOU Feng, LIU Shu, LIU Zhiqiang, SONG Fengrui. Application of Methanol and Ethanol in Argon-Direct Real Time Mass Spectrometry Analysis [J]. Chinese Journal of Applied Chemistry, 2017, 34(6): 729-732.
[13]	BI Weihui, ZHENG Jifu, ZHANG Suobo. Preparation and Characterization of Sulfonated Poly(p-phenylene-co-aryl ether ketone) for Proton Exchange Membranes [J]. Chinese Journal of Applied Chemistry, 2017, 34(10): 1117-1126.
[14]	HUANG Huodi,ZHANG Xiaofeng,ZHANG Yi,LE Lijuan,Lin Shen. Synthesis of Pt/{Reduced Graphene Oxide/Polyoxometalates}_n Composite Films and Their Electrocatalytic Performance [J]. Chinese Journal of Applied Chemistry, 2017, 34(10): 1209-1220.
[15]	BI Weihui, ZHENG Jifu, ZHANG Suobo. Preparation and Characterization of Sulfonated Poly(p-phenylene-co-aryl ether ketone) for Proton Exchange Membranes [J]. Chinese Journal of Applied Chemistry, 2017, 34(10): 0-0.

Laser Stimulated Oxidative Coupling of Ethanol

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments