Catalytic Performance of Pd-Cu/ZrO2 Catalyst for Hydrogenation of Carbon Dioxide to Methanol

doi:10.11944/j.issn.1000-0518.2020.02.190211

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (2): 160-167.DOI: 10.11944/j.issn.1000-0518.2020.02.190211

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Catalytic Performance of Pd-Cu/ZrO₂ Catalyst for Hydrogenation of Carbon Dioxide to Methanol

GAO Jia^a,SONG Fujiao^b,CHENG Wenqiang^c,GE Yan^c,XU Qi^a^*()

^aSchool of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,Jiangsu 212013,China
^bSchool of Environmental Science Engineering,Yancheng Institute of Technology,Yancheng,Jiangsu 224051,China
^cSchool of Chemistry and Chemical Engineering,Yancheng Institute of Technology,Yancheng,Jiangsu 224051,China

Received:2019-07-31 Accepted:2019-11-04 Published:2020-02-01 Online:2020-02-06
Contact: XU Qi
Supported by:
Supported by the National Natural Science Foundation of China(No.21802119)

Abstract

Abstract:

Cu/ZrO₂ catalysts with the Cu/Zr molar ratio of 1:1, 1:2, 1:4 and 1:8 were prepared by the sol-gel method. When n(Cu):n(Zr)=1:4, a high CO₂ conversion (8.0%) with methanol selectivity of 59.5% was achieved. To increase CO₂ conversion and CH₃OH selectivity, Pd-Cu/ZrO₂ catalyst with the Cu/Zr molar ratio of 1:4 and 1 % mass fraction of Pd was synthesized by the impregnation method. The results showed that CO₂ conversion and CH₃OH yield over the Pd-Cu/ZrO₂ catalyst were 40.0% and 80.9% higher than that over the Cu/ZrO₂ catalyst at 250 ℃, 2 MPa, 12000 mL/(g·h) and V(H₂):V(CO₂)=3:1. Powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy analysis (FT-IR), N₂ adsorption-desorption (BET), X-ray photoelectron spectroscopy (XPS) and temperature-programmed reduction of H₂(H₂-TPR) results indicated that addition of Pd improved the dispersion and surface area of the catalyst. The strong interaction between Pd and Cu species leads to the shift of Cu2p to low binding energies and decreases the catalyst reduction temperature, which exhibits high catalytic performance for hydrogenation of CO₂.

Key words: sol-gel method, impregnation method, carbon dioxide hydrogenation, methanol

GAO Jia, SONG Fujiao, CHENG Wenqiang, GE Yan, XU Qi. Catalytic Performance of Pd-Cu/ZrO₂ Catalyst for Hydrogenation of Carbon Dioxide to Methanol[J]. Chinese Journal of Applied Chemistry, 2020, 37(2): 160-167.

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Catalytic Performance of Pd-Cu/ZrO₂ Catalyst for Hydrogenation of Carbon Dioxide to Methanol

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