Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (6): 69-72.

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Kinetics of Deep Oxidation of Toluene over Pt/NM、Pd/NM Catalysts

Luo Mengfei, Yuan Xianxin, Chen Min   

  1. Catalysis Institute Hangzhou University, Hangzhou 310028
  • Received:1994-03-09 Revised:1994-06-16 Published:1994-12-10 Online:1994-12-10

Abstract: The deep oxidation kinetics of toluene over PtINM and Pd/NM catalysts was studied in the presence of large excess of oxygen. The catalytic activity of Pt/NM was higher than that of Pd/NM. The rate of the catalytic oxydation could be described by equation The aparent activation energy(△E) and the heat of absorption(Q) of toluene on the catalyst surface were calculated as 49.9(kJ/mol),-29.6(kJ/mol)for Pt/NM and 94.2(kJ/mol),-19.1(kJ/mol)for Pd/NM respectively.

Key words: toluene, oxydation kinetics, Pt, Pd