Synthesis and Properties of Coordination Compounds of Au(Ⅲ) with 1-Hydroxy-2-(1H)-Pyridinethione and Its Methyl Derivatives

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (6): 73-76.

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Synthesis and Properties of Coordination Compounds of Au(Ⅲ) with 1-Hydroxy-2-(1H)-Pyridinethione and Its Methyl Derivatives

Song Baolin¹, Lu Xiangsheng¹, Niu Dezhong¹, Cao Yang¹, Lu Zaisheng¹, Li Jinliang¹, Wang Liyu²

1. Department of Chemistry, Xuzhou Teachers'COllege, Xuzhou 221009;
2. The Affiliatied Hospital of Xuzhou Medical CoIIege, Xuzhou

Received:1994-03-09 Revised:1994-06-21 Published:1994-12-10 Online:1994-12-10

Abstract

Abstract: Three new-type complexes,[AuL₂]OH (HL:1-hydroxy-2-(1H)-pyridine-thione and its 3- and 4-met hyl-derivatives),were prepared. They have been characterized by elemental analysis,UV,IR,¹H NMR,molar conductance and TG-DTA-DTG. Their redox properties have been investigated by cyclic voltammetry. The complexes having CH₃ substituent in pyridine ring showed a fairly high antibacterial activity.

Key words: gold complex, hydroxy pyridinethione, hydroxy methyl pyridinethione, antibacterial activity

Song Baolin, Lu Xiangsheng, Niu Dezhong, Cao Yang, Lu Zaisheng, Li Jinliang, Wang Liyu. Synthesis and Properties of Coordination Compounds of Au(Ⅲ) with 1-Hydroxy-2-(1H)-Pyridinethione and Its Methyl Derivatives[J]. Chinese Journal of Applied Chemistry, 1994, 0(6): 73-76.

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Synthesis and Properties of Coordination Compounds of Au(Ⅲ) with 1-Hydroxy-2-(1H)-Pyridinethione and Its Methyl Derivatives

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