Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (5): 83-86.
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Sun Yingji, Li Shunyu, Wang Fuquan, Chen Yaguang, Qu Lunyu
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Abstract: systematic study on the redox property of tungstogermanate isomers α- and β-MxHy[GeW9M3(H2O)3O37]·nH2O(M′=Bu4N+,K+;M=Cr3+,Mn2+,Co2+,Ni2+,Cu2+) was carried out by polarography and voltammetry in aqueous solution. A redox mechanism was proposed and the effects of substituted elements and the structure of anions on the redox property were discussed.The oxidation abilities of the α- and β-isomers were compared.
Key words: tungstogermanate heteropoly complex, transitiondement, substituted complex, redox property
Sun Yingji, Li Shunyu, Wang Fuquan, Chen Yaguang, Qu Lunyu. Redox Properties of Tungstogermanate Isomers Trisubstituted by Transition Elements[J]. Chinese Journal of Applied Chemistry, 1994, 0(5): 83-86.
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