Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (1): 24-27.
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Liu Yifan, Chen Dianbao, Dong Jiyuan, Tang Xueming
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Abstract: The effects of the conditioiis of reaction between MoCl5 and n-C7H15COOH on the number of chlorine atorn in MoCl15 substituted by functional group C7H15COO have been studied. The UV-Vis spectra of the exchange products MoCl5 m(n-C7H15COO)m were discussed and assigned. The catalytic activity of the molybdenum catalyst system containing MoCl5 m(n-C7H15COO)m for butadiene polymerization was found to be decreased rapidly with increasing the number of substituted chlorine atoms in MoCl5.
Key words: molybdenum pentachoride, octanoic acid, Ziegler- Natta catalyst, butadiene poly merization
Liu Yifan, Chen Dianbao, Dong Jiyuan, Tang Xueming. Products of Substituftion Reaction Between MoCl5 and C7H15COOH and Their Enects on Butadiene Polymerization[J]. Chinese Journal of Applied Chemistry, 1994, 0(1): 24-27.
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