Syntbcsis of saturatd Urushiol Crown Ether Rare EarthComplexes andthe Lanthanum(Ⅲ)Ion Selective Electrode Using the Same

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (1): 20-23.

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Syntbcsis of saturatd Urushiol Crown Ether Rare EarthComplexes andthe Lanthanum(Ⅲ)Ion Selective Electrode Using the Same

Pan Enting¹, Zhou Xuemei¹, Huang Zaifu²

1. Department of Chemistry, Guaiigxi Normal University, Guilin 541004;
2. Departmeiit of Environmental Science, Wuhan University, Wuhan

Received:1992-12-31 Revised:1993-10-12 Published:1994-02-10 Online:1994-02-10

Abstract

Abstract: The complexes of rare earth (Ln = La～Nd)with saturated urushiol crown ether (DSU30C10) have been synthesized in acetonitrile solution. The complexes have been characterized by elemental analysis, IR and UV spectra, molar conductance and differential thermal analysis,The lanthanutn iOn selective electrode with saturated urushiol crown ether as a neutral carrier exhibited linear responses in 1×10^-2～1×10^-6mol/L La(NO₃)₃. The electrode showed better selectivity than other La(Ⅲ)electrodes reported in literature。

Key words: urushiol, crown ether, rare earth complex, ion selective electrode

Pan Enting, Zhou Xuemei, Huang Zaifu. Syntbcsis of saturatd Urushiol Crown Ether Rare EarthComplexes andthe Lanthanum(Ⅲ)Ion Selective Electrode Using the Same[J]. Chinese Journal of Applied Chemistry, 1994, 0(1): 20-23.

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Syntbcsis of saturatd Urushiol Crown Ether Rare EarthComplexes andthe Lanthanum(Ⅲ)Ion Selective Electrode Using the Same

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