Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (4): 39-42.

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STUDY ON CATALYTIC ACTIVITY OF SUPPORTED METAL PHTHALOCYANINE(MPc)—Ⅱ. MPc LINKED TO THE SURFACE OF SILICA GEL AND ITS ACTIVATION ACTION ON OXYGEN

Zhang Weide, Zhan Ruiyun, Ye Xingkai, Wu Yue   

  1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022 Changchun
  • Received:1992-10-23 Revised:1993-03-05 Published:1993-08-10 Online:1993-08-10

Abstract: The MPcs (M=Fe2+, Co2+, Cu2+; Pc=phthalocyanine) were coordinated with —(CH2)3N(C2H5)2 group of SiO2,which had been linked with above group through organic synthesis.The UV-Vis diffuse reflection spectra revealed this supporting. ESR result indicated that only the supported CoPe and FePc were capable of reacting with O2 producing O2-.

Key words: metal phthalocyanine, supported catalyst, oxygen activation