Catalytic Oxygen Reduction Property of Carbon Nanotubes Supported Tetra-nitro-metal Phthalocyanines-MnO2 Dual Catalysts

doi:10.11944/j.issn.1000-0518.2019.01.180065

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (1): 97-106.DOI: 10.11944/j.issn.1000-0518.2019.01.180065

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Catalytic Oxygen Reduction Property of Carbon Nanotubes Supported Tetra-nitro-metal Phthalocyanines-MnO₂ Dual Catalysts

CHEN Fengying^a,LI Kezhi^b^*(),HU Guangzhi^c

^aShaanxi Key Laboratory of Tailings Comprehensive Utilization of Resources,College of Chemical Engineering and Modern Materials,Shangluo University,Shangluo,Shaanxi 726000,China
^bC/C Composites Research Center,State Key Laboratory of Solidification Processing,Northwestern Polytechnical University,Xi'an 710072,China
^cKey Laboratory of Chemistry of Plant Resources in Arid Regions,State Key Laboratory Basis of Xinjiang Indigenous Medicinal Plants Resource Utilization,Xinjiang Technical Institute of Physics and Chemistry,Chinese Academy of Science,Urumqi 830011,China

Received:2018-03-09 Accepted:2018-08-06 Published:2019-01-01 Online:2019-01-04
Contact: LI Kezhi
Supported by:
Supported by the National Natural Science Foundation of China(No.51432008, No.21677171), the Foundation of Shangluo University(No.17SKY027)

Abstract

Abstract:

The transition metal phthalocyanine has a high catalytic activity for oxygen reduction. MnO₂ can catalyze the oxygen reduction reaction. However, the use of transition metal phthalocyanine and MnO₂ as dual catalysts for oxygen reduction is quite few. Four types of carbon nanotubes supported tetra-nitro-metal phthalocyanines assemblies(CNT/TNMPc) were synthesized by phthalic anhydride-urea method. Dual catalyst CNT/TNMPc-MnO₂ was prepared via adding γ-MnO₂ into CNT/TNMPc. The optimal ratio of CNT/TNMPc to MnO₂ was obtained by means of cyclic voltammetry. Effects of central metal ions of CNT/TNMPc on the catalytic performance for oxygen reduction reactivity were investigated. The results show that the catalytic efficiency order of the dual catalyst for oxygen reduction reactivity is CNT/TNFePc-MnO₂>CNT/TNCoPc-MnO₂>CNT/TNNiPc-MnO₂>CNT/TNCuPc-MnO₂. All of those suggest that the catalytic activity of dual catalysts for oxygen reduction reaction is mainly affected by the nature of metal ions. In addition, the anti methanol performance of dual catalyst was tested in 0.1 mol/L KOH+0.5 mol/L CH₃OH electrolyte solution. The results indicate that methanol-tolerant abilities of the CNT/TNMPc-MnO₂ are excellent.

Key words: metal phthalocyanine, MnO₂, oxygen reduction reactivity, dual catalyst, carbon nanotubes

CHEN Fengying, LI Kezhi, HU Guangzhi. Catalytic Oxygen Reduction Property of Carbon Nanotubes Supported Tetra-nitro-metal Phthalocyanines-MnO₂ Dual Catalysts[J]. Chinese Journal of Applied Chemistry, 2019, 36(1): 97-106.

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Catalytic Oxygen Reduction Property of Carbon Nanotubes Supported Tetra-nitro-metal Phthalocyanines-MnO₂ Dual Catalysts

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