SYNTHESIS AND CHARACTERIZATION OF TERNERY COMPLEXES OF RARE EARTHS WITH HPMBP AND 1-NITROSO-2-NAPHTHOL

Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (4): 10-12.

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SYNTHESIS AND CHARACTERIZATION OF TERNERY COMPLEXES OF RARE EARTHS WITH HPMBP AND 1-NITROSO-2-NAPHTHOL

Qi Yulan, Yang Rudong

Department of Chemistry, Lanzhou University, 730000 Lanzhou

Received:1992-09-03 Revised:1993-03-08 Published:1993-08-10 Online:1993-08-10

Abstract

Abstract: Sixteen cornplexes of rare earth (RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y) with 1-pheny-3-methyl-4-benzoyl-pyrazolone-5 (HPMBP) and 1-nitroso-2-naphthol (NN) have been synthesized and characterized by elemental analysis, IR ¹HNMR and DTA measurements. The ternary complexes have a general formula RE:PMBP:NN=1:3:1(1:4:1 when RE=Ce(Ⅳ)). All the complexes are crystal in gray-violet colour. They are soluble in ethanol, acetone and benzene, insoluble in water, and air-stable at room temperature.

Key words: rare earth, phenylmethylbenzoylpyrazolone, nitrosonaphthol, ternary complex, synthesis

Qi Yulan, Yang Rudong. SYNTHESIS AND CHARACTERIZATION OF TERNERY COMPLEXES OF RARE EARTHS WITH HPMBP AND 1-NITROSO-2-NAPHTHOL[J]. Chinese Journal of Applied Chemistry, 1993, 0(4): 10-12.

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SYNTHESIS AND CHARACTERIZATION OF TERNERY COMPLEXES OF RARE EARTHS WITH HPMBP AND 1-NITROSO-2-NAPHTHOL

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