STUDIES ON THE COMPLEXES OF RARE EARTH WITH SULPHUR CONTAINING ORGANIC LIGANDS Ⅳ.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF LIGHT RARE EARTH WITH 3-PHENYL-5-(FURYL-2)PYRAZOLINE DITHIOFORMATE

Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (3): 83-86.

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STUDIES ON THE COMPLEXES OF RARE EARTH WITH SULPHUR CONTAINING ORGANIC LIGANDS Ⅳ.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF LIGHT RARE EARTH WITH 3-PHENYL-5-(FURYL-2)PYRAZOLINE DITHIOFORMATE

Zhang Weiguang¹, Tang Ning², Gan Xinmin², Tan Minyu²

1. Department of Chemistry, Jiangxi Normal University;
2. Department of Chemistry, Lanzhou University, Lanzhou 730000

Received:1991-01-14 Revised:1991-10-11 Published:1992-06-10 Online:1992-06-10

Abstract

Abstract: Five solid complexes of rare earth with 3-phenyl-5-(furyl-2)pyrazoline dithioformate RE(S₂CNC₁₃H₁₁NO)₃·nH₂O(RE=La, Pr, Nd, Sm, Eu; n=2,4) have been synthesized in dry N₂ atmosphere and characterized by elemental analyses, IR spectra, molar con uctance, thermal analyses and fluorescence spectra. The results show that ligands are ccordinated to RE ion through two sulphur atom donors.

Key words: La, Pr, Nd, Sm, Eu, 3-phenyl-5-(furyl) pyrazoline dithioformate, complex, synthesis, physical property

Zhang Weiguang, Tang Ning, Gan Xinmin, Tan Minyu. STUDIES ON THE COMPLEXES OF RARE EARTH WITH SULPHUR CONTAINING ORGANIC LIGANDS Ⅳ.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF LIGHT RARE EARTH WITH 3-PHENYL-5-(FURYL-2)PYRAZOLINE DITHIOFORMATE[J]. Chinese Journal of Applied Chemistry, 1992, 0(3): 83-86.

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STUDIES ON THE COMPLEXES OF RARE EARTH WITH SULPHUR CONTAINING ORGANIC LIGANDS Ⅳ.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF LIGHT RARE EARTH WITH 3-PHENYL-5-(FURYL-2)PYRAZOLINE DITHIOFORMATE

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