SYNTHESIS AND CHARACTERIZATION OF LANTHANIDE COMPLEXES WITH DIETHYLENE GLYCOL DI(O-HY-DROXYPHENYL) ETHER

Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (2): 12-17.

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SYNTHESIS AND CHARACTERIZATION OF LANTHANIDE COMPLEXES WITH DIETHYLENE GLYCOL DI(O-HY-DROXYPHENYL) ETHER

Yao Kemin¹, Cai Lezhen¹, Bao Zhengcao¹, Shen Lianfang², Tian Qingping²

1. Department of Chemistry, Zhejiang University, Hangzhou 310027;
2. Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, Academia Sinica, Wuhan

Received:1991-02-25 Revised:1991-07-13 Published:1992-04-10 Online:1992-04-10

Abstract

Abstract: Forteen novel complexes of lanthanide perchlorate and nitrate with diethylene glycol di(o-hydroxyphenyl) ether (EO₂(HOP)₂) (EO=ethylene oxide,HOP=o-hydroxyphenyl) have been synthesized and characterized. Compositions of the complexes were comfirmed as Ln·(ClO₄)₃. EO₂(HOP)₂·nH₂O (Ln=La-Eu, n=10; Ln=Gd, Dy-Tm,Y, n=7) ,La₃(NO₃)₉·(EO₂(HOP)₂)₂·3H₂O and La(ClO₄)₃·EO₂H(OP)₂·5H₂O respectively. Some properties of the title coordination compounds were investigated by IR-, UV-Spectra, ¹HNMR and ¹³C NMR.Effects of eounterion, kinds of solvents and terminal group ligand on eomplexation were also discussed.

Key words: lanthanide, yttrium, acyclic polyether, complex, NMR

Yao Kemin, Cai Lezhen, Bao Zhengcao, Shen Lianfang, Tian Qingping. SYNTHESIS AND CHARACTERIZATION OF LANTHANIDE COMPLEXES WITH DIETHYLENE GLYCOL DI(O-HY-DROXYPHENYL) ETHER[J]. Chinese Journal of Applied Chemistry, 1992, 0(2): 12-17.

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SYNTHESIS AND CHARACTERIZATION OF LANTHANIDE COMPLEXES WITH DIETHYLENE GLYCOL DI(O-HY-DROXYPHENYL) ETHER

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