POLYSILOXANE CATALYSTS WITH AMINO ACID SIDE CHAIN Ⅵ.SYNTHESIS AND HYDROGENATION ACTIVITY OF POLY-R-(LYSINE)PROPYLSILOXANE PALLADIUM CATALYSTS

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (6): 6-9.

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POLYSILOXANE CATALYSTS WITH AMINO ACID SIDE CHAIN Ⅵ.SYNTHESIS AND HYDROGENATION ACTIVITY OF POLY-R-(LYSINE)PROPYLSILOXANE PALLADIUM CATALYSTS

Liu JiWan, You Jiang, Wang Xixin, Tong Lixin

Department of Chemistry, Wuhan University, Wuhan 430072

Received:1990-08-21 Revised:1991-01-03 Published:1991-12-10 Online:1991-12-10

Abstract

Abstract: The poly-r-(lysine) propylsiloxane supported palladium catalysts were synthesized andcharacterized. The catalysts showed a high activity for acrylonitrile hydrogenation whenthe molar ratio of N/Pd was 3.4. The hydrogenation of cyclopentadiene appeared to be atwo-stage process. The solvents have an obvious influence on the hydrogenation activity ofthe catalyst.

Key words: polymeric palladium catalyst, L-lysine, polysiloxane, hydrogenation, acrylonitrile, cyclopentadiene

Liu JiWan, You Jiang, Wang Xixin, Tong Lixin. POLYSILOXANE CATALYSTS WITH AMINO ACID SIDE CHAIN Ⅵ.SYNTHESIS AND HYDROGENATION ACTIVITY OF POLY-R-(LYSINE)PROPYLSILOXANE PALLADIUM CATALYSTS[J]. Chinese Journal of Applied Chemistry, 1991, 0(6): 6-9.

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POLYSILOXANE CATALYSTS WITH AMINO ACID SIDE CHAIN Ⅵ.SYNTHESIS AND HYDROGENATION ACTIVITY OF POLY-R-(LYSINE)PROPYLSILOXANE PALLADIUM CATALYSTS

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