CRYSTAL STRUCTURE OF K4H[SiMo11VO40]·18H2O(1) AND K4H2[PMo9V3O40]·18H2O(2)

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (5): 42-48.

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CRYSTAL STRUCTURE OF K₄H[SiMo₁₁VO₄₀]·18H₂O(1) AND K₄H₂[PMo₉V₃O₄₀]·18H₂O(2)

Jin Zhongsheng¹, Wei Gecheng¹, Piao Jinzhi², Shan Yongkui³

1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2. Department of Chemistry, Yan Bian University, Jilin Yanlbian;
3. Department of Chemistry, Harbin Normal University, Harbin

Received:1990-04-04 Revised:1990-07-03 Published:1991-10-10 Online:1991-10-10

Abstract

Abstract: The crystal structures of the title compounds were determined by single crystal X-raydiffractometry at - 90℃。The complexes crystallize in tetragonal space groups P42₁c[P4/ mnc] with Z = 2[2].Lattice parameters are a = 12.540(2) [12.515(3)], c = 17.565(5) [17.636(7)]Å, V = 2762 (1) [2762 (2)]Å^ε.The structures were solved by direct methods and Fouriertechniques and refined by least-squares techniques to R = 0.059[0.057] for 1672[788] reflec-tions.Si in compound (1) is 4-coordinated, Si-O = 1.58Å.M(M = Mo, V) is 6-coordinated,M-O = 1.64 - 2.37Å.K is 7-coordinated, K-O = 2.80—3.11Å.In compound (2), PO₄ isdisordered, P-O = 1.51Å, M-O = 1.63—2.47Å, K is 7-coordinate, K—O = 2.85～3.10Å.Bothstructures are in network.

Key words: heteropolyacid, crystal structure

Jin Zhongsheng, Wei Gecheng, Piao Jinzhi, Shan Yongkui. CRYSTAL STRUCTURE OF K₄H[SiMo₁₁VO₄₀]·18H₂O(1) AND K₄H₂[PMo₉V₃O₄₀]·18H₂O(2)[J]. Chinese Journal of Applied Chemistry, 1991, 0(5): 42-48.

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CRYSTAL STRUCTURE OF K₄H[SiMo₁₁VO₄₀]·18H₂O(1) AND K₄H₂[PMo₉V₃O₄₀]·18H₂O(2)

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