SYNTHESIS,CRYSTAL AND MOLECULAR STRUCTURES OF AZIDO CHROMIUM(Ⅲ)TETRAPHENYLPORPHYRIN PYRIDINE COMPLEX

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (3): 67-70.

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SYNTHESIS,CRYSTAL AND MOLECULAR STRUCTURES OF AZIDO CHROMIUM(Ⅲ)TETRAPHENYLPORPHYRIN PYRIDINE COMPLEX

Shu Huoming, Gu Shuzhen, Liu Yongsheng, Jin Rishen

Changchun Institute of Applied Chemisstry, Academia Sinica, Changchun 13002

Received:1990-04-04 Revised:1990-05-29 Published:1991-06-10 Online:1991-06-10

Abstract

Abstract: The crystal structure of Cr(Ⅲ) TPP (N₃) Py was determined on a Nicolet R3m/E four-circle diffractometer with X-ray intensity data being collected in 3.0°<2θ<34°.The spacegroup is P2_1/n with a=13.032(4)Å, b = 23.689(5)Å, c= 14.906(2)Å, β= 103.67°, Z = 4.The structure was solved by heavy atom method and Fouirer techniques, and refined byblockdiagonal matric least-squares to a final R = 0.050.Bond distances are as follows:Cr-N_N3 2.004Å; Cr-N_{p_y} 2.135Å; the average Cr-N_Pyrrole 2.031Å.

Key words: porphyrin complex, crystal structure, X-ray diffractometry, azido chromium(Ⅲ)tetraphenylporphyrin pyridine complex

Shu Huoming, Gu Shuzhen, Liu Yongsheng, Jin Rishen. SYNTHESIS,CRYSTAL AND MOLECULAR STRUCTURES OF AZIDO CHROMIUM(Ⅲ)TETRAPHENYLPORPHYRIN PYRIDINE COMPLEX[J]. Chinese Journal of Applied Chemistry, 1991, 0(3): 67-70.

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SYNTHESIS,CRYSTAL AND MOLECULAR STRUCTURES OF AZIDO CHROMIUM(Ⅲ)TETRAPHENYLPORPHYRIN PYRIDINE COMPLEX

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