TERPOLYMERIZATION OF CO2,PROPYLENE OXIDE AND TOLYLENE DIISOCYANATE

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (1): 78-81.

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TERPOLYMERIZATION OF CO₂,PROPYLENE OXIDE AND TOLYLENE DIISOCYANATE

Peng Han, Chen Liban, Yang Shuying, Su Yue

Guangzhou Institute of Chemistry, Academia Sinica, Guangzhou 510650

Received:1990-04-05 Revised:1990-08-14 Published:1991-02-10 Online:1991-02-10

Abstract

Abstract: CO₂, propylene oxide (PO), and tolylene diisocyanate (TDI) were catalytically terpoly-merized to form a polycarbonate-polyurethane (PCPU).The addition of TDI resulted inchain extending, branching and crosslinking.The terpolymer was thermally more stablethan the copolymer of CO₂ and propylene oxide.

Key words: carbon dioxide, Propylene oxide, tolylene diisocyanate, terpolymerization, coordination catalyst

Peng Han, Chen Liban, Yang Shuying, Su Yue. TERPOLYMERIZATION OF CO₂,PROPYLENE OXIDE AND TOLYLENE DIISOCYANATE[J]. Chinese Journal of Applied Chemistry, 1991, 0(1): 78-81.

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TERPOLYMERIZATION OF CO₂,PROPYLENE OXIDE AND TOLYLENE DIISOCYANATE

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