SYNTHESES,STRUCTURES AND PROPERTIES OF η6-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C6H6)(AlCl4)3C6H6(RE=La,Nd)AND THE MOLECULAR STRUCTURE OF Nd(C6H6)(AlCl4)3C6H6

Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (6): 23-27.

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SYNTHESES,STRUCTURES AND PROPERTIES OF η⁶-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C₆H₆)(AlCl₄)₃C₆H₆(RE=La,Nd)AND THE MOLECULAR STRUCTURE OF Nd(C₆H₆)(AlCl₄)₃C₆H₆

Fan Baochen, Lin Yonghua, Shen Qi

Laboratory of Rare-earth Chemistry and Physics Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received:1989-11-30 Revised:1990-04-20 Published:1990-12-10 Online:1990-12-10

Abstract

Abstract: AlCl₃ which was activated by heating with aluminum powder reacts with RECl₃ in benzene solution giving two new neutral arene complexes, RE(C₆H₆)(AlCl₄)₃C₆H₆(RE = La, Nd).The complexes were characterized by elemental analysis and IR spectra measurement. The molecular structure of necdium containing complex has been determined. It's isomorphous and isostructural with Sm(C₆H₆)(AlCl₄)₃C₆H₆. The Nd-C and Nd-Cl bond lengths are respectively longer than Sm-C and Sm-Cl bond lengths in corresponding Sm-containingcomplex

Key words: light lanthanoids, neutral arene complex, synthesis, structure

Fan Baochen, Lin Yonghua, Shen Qi. SYNTHESES,STRUCTURES AND PROPERTIES OF η⁶-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C₆H₆)(AlCl₄)₃C₆H₆(RE=La,Nd)AND THE MOLECULAR STRUCTURE OF Nd(C₆H₆)(AlCl₄)₃C₆H₆[J]. Chinese Journal of Applied Chemistry, 1990, 0(6): 23-27.

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SYNTHESES,STRUCTURES AND PROPERTIES OF η⁶-ARENE ORGANOLANTHANOIDS Ⅲ.SYNTHESIS OF RE(C₆H₆)(AlCl₄)₃C₆H₆(RE=La,Nd)AND THE MOLECULAR STRUCTURE OF Nd(C₆H₆)(AlCl₄)₃C₆H₆

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