SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX OF SAMARIUM WITH DIMETHYL PHOSPHATE

Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (6): 53-57.

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SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX OF SAMARIUM WITH DIMETHYL PHOSPHATE

Li Laiming¹, Lin Yonghua¹, Zeng Guangfu¹, Ma Aizeng⁴

1. Changchun Institute of Applied Chemistry, Academia Sinica;
2. Department of Soil Chemistry, Jilin University of Agriculture, Changchun

Received:1988-12-16 Revised:1989-06-13 Published:1989-12-10 Online:1989-12-10

Abstract

Abstract: The title. complex has been synthesized and characterized by elemental analysis, FT-IR,Raman spectrometric analysis and X-ray diffractometry. The crystal of the complex is monoclinic with space group P2₁/c and a=10.434(4),b=16.541(3),C=10.804(4)Å,β=111.75(3)°, V=1731.7(9)Å³ for Z=4. Dimetbyl phosphate anions coordinate with samarium atoms through double O-P-O bridges to form a Epecial network of ring-linking-ring, each of which consists of twenty-four atoms. The coordination number of Sm is six,and the coordinate polyhedron about Sm is a slightly distorted octahedron.

Key words: Complex of samarium with dimethyl phosphate, Crystal structure, Vibration spectrometry

Li Laiming, Lin Yonghua, Zeng Guangfu, Ma Aizeng. SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX OF SAMARIUM WITH DIMETHYL PHOSPHATE[J]. Chinese Journal of Applied Chemistry, 1989, 0(6): 53-57.

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SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX OF SAMARIUM WITH DIMETHYL PHOSPHATE

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