SIMULTANEOUS SPECTROPHOTOMETRIC DETERMINATION OF ARSENIC AND ANTIMONY

Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (4): 84-86.

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SIMULTANEOUS SPECTROPHOTOMETRIC DETERMINATION OF ARSENIC AND ANTIMONY

Qiu Sunqing, Wang Bingwu

Changchun Institute of Applied Chemistry, Academia Sinica

Received:1988-06-29 Revised:1989-01-27 Published:1989-08-10 Online:1989-08-10

Abstract

Abstract: A simnltaneous spectrophoto metric method for Sb and As determination has been.established. SbH₃ and AsH₃, produced by addition of a KBH₄ tablet to Sb³⁺ and As³⁺in tartaric solution,were absorbed by a 95% alcohol solution of Fe³⁺-1,10 phenathrolineand a mixed solution of AgNO₃, PVA and alcohol. The absorbances were measured at 400nm for As and 510nm for Sb. Tolerance levels of various ions were given. The detection limitswere 0.09ppm (3 s) for Sb and 0.05ppm (3 s) for As. The method is simple, rapid, and sensitive.

Key words: Arsenic, Antimony, Microanalysis, Spectrophotometry

Qiu Sunqing, Wang Bingwu. SIMULTANEOUS SPECTROPHOTOMETRIC DETERMINATION OF ARSENIC AND ANTIMONY[J]. Chinese Journal of Applied Chemistry, 1989, 0(4): 84-86.

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SIMULTANEOUS SPECTROPHOTOMETRIC DETERMINATION OF ARSENIC AND ANTIMONY

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