The synthesis and Properties of Compound [InAsS4(2,2’-bipy)]2 : AsS43- (As(Ⅲ)) as One Part of the Structure

doi:10.3724/SP.J.1095.2011.00200

Chinese Journal of Applied Chemistry ›› 2011, Vol. 28 ›› Issue (01): 77-82.DOI: 10.3724/SP.J.1095.2011.00200

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The synthesis and Properties of Compound [InAsS₄(2,2’-bipy)]₂ : AsS₄^3- (As(Ⅲ)) as One Part of the Structure

WANG Zhen-Qing^1,2, WANG Cheng^1*

(1.Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022；
2.Graduate School of Chinese Academy of Sciences,Beijing)

Received:2010-04-07 Revised:2010-07-25 Published:2011-01-10 Online:2011-01-10
Contact: Cheng Wang

Abstract

Abstract:

Compound [InAsS4(2，2′-bipy)]2, which contains AsS3-4(As(Ⅲ)) unit, was synthesized by the hydrothermal method. The compound crystalizes in monoclinic space group P21/c with a=0.89799(9) nm, b=2.1794(2) nm, c=1.43736(14) nm, β=91.274(2)°, V=2.8123(5) nm3. In this compound, the AsS3-4(As(Ⅲ)) unitis stabilized by metal-amino complex [In(2，2′-bipy)]3+. The effect of metal charge on the formation of this product was discussed and the band gap of the as-synthesized semiconductor is found to be 1.35 eV.

Key words: metal arsenic sulphides, metal-amino complexes, hydrothermal synthesis

CLC Number:

O612.5

WANG Zhen-Qing1,2, WANG Cheng1*. The synthesis and Properties of Compound [InAsS₄(2,2’-bipy)]₂ : AsS₄^3- (As(Ⅲ)) as One Part of the Structure[J]. Chinese Journal of Applied Chemistry, 2011, 28(01): 77-82.

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The synthesis and Properties of Compound [InAsS₄(2,2’-bipy)]₂ : AsS₄^3- (As(Ⅲ)) as One Part of the Structure

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