Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (3): 57-58.

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A NEW METHOD FOR SYNTHESIS OF β,γ-UNSATURATED AMIDES

Li Chaojun1, Li Jisheng1, Chen Deheng2   

  1. 1. Institute of Chemistry, Academia Sinica, Beijing;
    2. Department of Chemistry, McGill University, Canada
  • Received:1988-07-13 Revised:1988-10-14 Published:1989-06-10 Online:1989-06-10

Abstract: Reaction of vinylalanate obtained from the readily available. dialkylvinylalane and n-butyl lithium with α-halo-amides produced the corresponding β,γ-unsaturated amides, withclean retention of the configuration. The yields were 35% to 70%.

Key words: Unsaturated amide, Vinylalane, Synthesis, Ate-complex