SYTHESES OF CYCLOPENTANYL(OR ALLYL)CYCLOPENTA-DIENYL LATHANOID DIOHLORIDE TETRAHYDROFURANATE COMPLEXES

Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (3): 37-41.

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SYTHESES OF CYCLOPENTANYL(OR ALLYL)CYCLOPENTA-DIENYL LATHANOID DIOHLORIDE TETRAHYDROFURANATE COMPLEXES

Wang Yuling¹, Chen Wenqi¹, Zhang Bin²

1. Changchun Institute of Applied Chemistry, Academia Sinica;
2. Department of Chemistry, Heilongjiang University, Harbin

Received:1988-07-23 Revised:1988-10-20 Published:1989-06-10 Online:1989-06-10

Abstract

Abstract: In this paper the syntheses of cyclopentanyl (ora llyl) cyclopentadienyl lanthanoid dichlo-ride tetrahydrofuranate complexes are first reported. The complexes of C₅H₉C₅H₄·LnCl₂-nTHF and C₃H₅C₅H₄LnCl₂·nTHF (C₃H₉C₅H₄= cyclopentanyl cyclopentadienyl; C₃H₅C₅H₄=allylcyclopentadienyl; Ln = Nd, Sm, Gd; n = 0, 1, 2, 3) are identified by elemental ana-lysis, thermal analysis, IR, MS and NMR measurements. The crysal structure of thereaction intermediate C₅H₉C₅H₄Na·THF was determined by the x-ray diffraction method.

Key words: Cyclopentanyl cyclopentadienyl lanthanoid dichloride, Allyl cyolopentadienyl lanthanoid dichoride, Cyclopentanylcyclopentodienyl sodium, Crystal structure

Wang Yuling, Chen Wenqi, Zhang Bin. SYTHESES OF CYCLOPENTANYL(OR ALLYL)CYCLOPENTA-DIENYL LATHANOID DIOHLORIDE TETRAHYDROFURANATE COMPLEXES[J]. Chinese Journal of Applied Chemistry, 1989, 0(3): 37-41.

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SYTHESES OF CYCLOPENTANYL(OR ALLYL)CYCLOPENTA-DIENYL LATHANOID DIOHLORIDE TETRAHYDROFURANATE COMPLEXES

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