CRYSTAL STRUCTURE OF Zn(Vitamin B1) COORDINATION COMPLEX

Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (2): 40-42.

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CRYSTAL STRUCTURE OF Zn(Vitamin B₁) COORDINATION COMPLEX

Liu Pengjun, Wei Gecheng, Jin Zhongsheng, Wang Wenyun

Changchun Institute of Applied Chemistry, Academia Sinica

Received:1988-03-12 Revised:1988-08-29 Published:1989-04-10 Online:1989-04-10

Abstract

Abstract: The crystal structure of the title compound was determined by X-ray diffractometry.The complex crystallizes in monoclinic space group C2/c with Z= 8. Lattice parametersare: a =25.747(5), b= 8.461(0), c = 17.407(3)Å and β= 105.79(1)°. The structure wassolved by Patterson and Fourier techniques and refined by least-squares to a final R valueof 0.0283. The Zn(Ⅱ) ion is coordinated by three chloroligands and the atom N(1) of thepyrimidine ring of thiamine molecule, forming a slightly distorted tetrahedral coordinationpolyhedron. The average Zn-Cl distance is 2.266Å and the Zn-N bond length is2.042(4)Å.

Key words: Zn(Vitamin B₁) complex, Crystal structure

Liu Pengjun, Wei Gecheng, Jin Zhongsheng, Wang Wenyun. CRYSTAL STRUCTURE OF Zn(Vitamin B₁) COORDINATION COMPLEX[J]. Chinese Journal of Applied Chemistry, 1989, 0(2): 40-42.

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CRYSTAL STRUCTURE OF Zn(Vitamin B₁) COORDINATION COMPLEX

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