MOLECULAR AND CRYSTAL STRUCTURE OF TETRA(p-METHOXY PHEHYL)PORPHYRIN MAHGANESE(Ⅲ)CHLORIDE COMPLEX

Chinese Journal of Applied Chemistry ›› 1988, Vol. 0 ›› Issue (4): 50-53.

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MOLECULAR AND CRYSTAL STRUCTURE OF TETRA(p-METHOXY PHEHYL)PORPHYRIN MAHGANESE(Ⅲ)CHLORIDE COMPLEX

Zheng Jinghe, Jin Shongchun, Jin Zhungsheng, Jin Rizhen

Changchun Institute of Applied Chemistry, Academia Sincia

Received:1987-02-23 Revised:1987-01-23 Published:1988-08-10 Online:1988-08-10

Abstract

Abstract: The crystals of the title compound are orthorhombic with space group P_bca and a=23.3973(6)Å,b=22.5524(7)Å, c=15.1043(2)Å V=7970.02Å³, for Z=8.Diffracted intensities were collected on a Nicolet XRD R3 four-circle diffractometer using MoK_α radiation.The scanning technique was employed with a scan range 3°<2θ<45°.All independent reflections were 5200 among which 2859 reflections were observable (Ⅰ>3σ(Ⅰ)).The structure was determined by the heavy atom method and refined by block-diagonal matric least-square method.The average Mn—N bond length is 2.005Å and Mn—Cl bond length is 2.370(3)Å.

Key words: Porphyrin complex, Crystal structure, X-ray diffractometry

Zheng Jinghe, Jin Shongchun, Jin Zhungsheng, Jin Rizhen. MOLECULAR AND CRYSTAL STRUCTURE OF TETRA(p-METHOXY PHEHYL)PORPHYRIN MAHGANESE(Ⅲ)CHLORIDE COMPLEX[J]. Chinese Journal of Applied Chemistry, 1988, 0(4): 50-53.

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MOLECULAR AND CRYSTAL STRUCTURE OF TETRA(p-METHOXY PHEHYL)PORPHYRIN MAHGANESE(Ⅲ)CHLORIDE COMPLEX

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