Research Progress in Online Gas Chromatography Analysis Technology

doi:10.19894/j.issn.1000-0518.240178

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (11): 1552-1564.DOI: 10.19894/j.issn.1000-0518.240178

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Research Progress in Online Gas Chromatography Analysis Technology

Zhi-Rong GAO¹^,²(), Yun-Long AI², Jian-Lin LIU²

^1.Shanghai Xingpu Technology Co. ，Ltd. ，Shanghai 201208，China
^2.Zhong An Hao Yuan （Shanghai ） Hydrogen Energy Technology Co. ，Ltd. ，Shanghai 201208，China

Received:2024-06-05 Accepted:2024-10-13 Published:2024-11-01 Online:2024-12-04
Contact: Zhi-Rong GAO
About author:zhizi7752@163.com

Abstract

Abstract:

The online gas chromatography analysis is a multidisciplinary area that uses an online sampling system to transfer chemical process materials to a pre-treatment system， in which interference components such as dust and corrosive compounds are removed， then the materials are seat to a gas chromatograph for separation， detection and quantitation. Finally， the chromatographic data is automatically processed， remotely sent， and alarmed through a data processing platform. The online gas chromatography analysis technology has been applied in three aspects， i.?e. micro-reactor， laboratory online analysis， and industrial chromatography. This article reviews the development history of online gas chromatography technology briefly， and the research and applications are also introduced via the authors′ 20-year-experience. Besides， the challenges and opportunities faced by this technique are discussed in detail， and the future development of domestic online gas chromatographic instrumentation is prospected.

Key words: Online gas chromatography, Micro-reactor online gas chromatography, Laboratory online gas chromatography, Process chromatography

CLC Number:

O657.7

Zhi-Rong GAO, Yun-Long AI, Jian-Lin LIU. Research Progress in Online Gas Chromatography Analysis Technology[J]. Chinese Journal of Applied Chemistry, 2024, 41(11): 1552-1564.

Figures/Tables 12

References 37

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	Reactor 1						Reactor 2
Name	Number of measurements						Number of measurements
Name	1	2	3	4	5	1	2	3	4	5
Methane	0.472	0.451	0.450	0.450	0.450	0.453	0.451	0.450	0.450	0.450
Ethane	0.955	0.955	0.955	0.955	0.955	0.960	0.958	0.957	0.957	0.957
Ethene	94.12	94.16	94.15	94.12	94.12	94.17	94.17	94.11	94.12	94.12
Propane	0.479	0.478	0.478	0.478	0.478	0.481	0.479	0.479	0.480	0.480
Propylene	0.507	0.508	0.508	0.509	0.509	0.508	0.508	0.510	0.510	0.510
Trans-2-butene	0.985	0.978	0.982	0.991	0.991	0.969	0.973	0.995	0.989	0.988
N-Butene	0.993	0.989	0.991	0.996	0.996	0.986	0.987	0.998	0.995	0.995
Isobutene	0.487	0.487	0.487	0.489	0.489	0.485	0.486	0.490	0.489	0.489
Cis-2-butene	0.497	0.492	0.493	0.497	0.497	0.487	0.490	0.499	0.496	0.496
1，3-Butadiene	0.508	0.504	0.506	0.512	0.512	0.499	0.500	0.514	0.511	0.510
	Reactor 3					Reactor 4
Name	Number of measurements					Number of measurements
Name	1	2	3	4	5	1	2	3	4	5
Methane	0.454	0.452	0.452	0.451	0.451	0.450	0.450	0.449	0.449	0.449
Ethane	0.959	0.957	0.957	0.957	0.956	0.958	0.957	0.957	0.957	0.957
Ethene	94.15	94.16	94.10	94.13	94.12	94.10	94.12	94.09	94.10	94.10
Propane	0.479	0.478	0.479	0.479	0.479	0.481	0.480	0.481	0.480	0.480
Propylene	0.509	0.508	0.511	0.510	0.510	0.511	0.510	0.512	0.511	0.511
Trans-2-butene	0.979	0.978	0.996	0.988	0.991	0.994	0.989	0.999	0.995	0.997
N-Butene	0.990	0.988	0.999	0.994	0.995	1.000	0.997	1.002	1.000	1.001
Isobutene	0.487	0.486	0.491	0.488	0.489	0.491	0.490	0.493	0.491	0.492
Cis-2-butene	0.492	0.491	0.499	0.496	0.497	0.499	0.497	0.501	0.499	0.500
1，3-Butadiene	0.505	0.503	0.515	0.510	0.512	0.513	0.510	0.516	0.514	0.515

	Reactor 1						Reactor 2
Name	Number of measurements						Number of measurements
Name	1	2	3	4	5	1	2	3	4	5
Methane	0.472	0.451	0.450	0.450	0.450	0.453	0.451	0.450	0.450	0.450
Ethane	0.955	0.955	0.955	0.955	0.955	0.960	0.958	0.957	0.957	0.957
Ethene	94.12	94.16	94.15	94.12	94.12	94.17	94.17	94.11	94.12	94.12
Propane	0.479	0.478	0.478	0.478	0.478	0.481	0.479	0.479	0.480	0.480
Propylene	0.507	0.508	0.508	0.509	0.509	0.508	0.508	0.510	0.510	0.510
Trans-2-butene	0.985	0.978	0.982	0.991	0.991	0.969	0.973	0.995	0.989	0.988
N-Butene	0.993	0.989	0.991	0.996	0.996	0.986	0.987	0.998	0.995	0.995
Isobutene	0.487	0.487	0.487	0.489	0.489	0.485	0.486	0.490	0.489	0.489
Cis-2-butene	0.497	0.492	0.493	0.497	0.497	0.487	0.490	0.499	0.496	0.496
1，3-Butadiene	0.508	0.504	0.506	0.512	0.512	0.499	0.500	0.514	0.511	0.510
	Reactor 3					Reactor 4
Name	Number of measurements					Number of measurements
Name	1	2	3	4	5	1	2	3	4	5
Methane	0.454	0.452	0.452	0.451	0.451	0.450	0.450	0.449	0.449	0.449
Ethane	0.959	0.957	0.957	0.957	0.956	0.958	0.957	0.957	0.957	0.957
Ethene	94.15	94.16	94.10	94.13	94.12	94.10	94.12	94.09	94.10	94.10
Propane	0.479	0.478	0.479	0.479	0.479	0.481	0.480	0.481	0.480	0.480
Propylene	0.509	0.508	0.511	0.510	0.510	0.511	0.510	0.512	0.511	0.511
Trans-2-butene	0.979	0.978	0.996	0.988	0.991	0.994	0.989	0.999	0.995	0.997
N-Butene	0.990	0.988	0.999	0.994	0.995	1.000	0.997	1.002	1.000	1.001
Isobutene	0.487	0.486	0.491	0.488	0.489	0.491	0.490	0.493	0.491	0.492
Cis-2-butene	0.492	0.491	0.499	0.496	0.497	0.499	0.497	0.501	0.499	0.500
1，3-Butadiene	0.505	0.503	0.515	0.510	0.512	0.513	0.510	0.516	0.514	0.515

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Research Progress in Online Gas Chromatography Analysis Technology

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