MoS2 and Its Modified Membranes for Heavy Metals and Radionuclides Removal from Water

doi:10.19894/j.issn.1000-0518.230335

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (2): 230-242.DOI: 10.19894/j.issn.1000-0518.230335

• Review • Previous Articles

MoS₂ and Its Modified Membranes for Heavy Metals and Radionuclides Removal from Water

Yan-Jun ZHANG, Yu YANG(), Li-An HOU()

State Key Laboratory of Water Environment Simulation，School of Environment，Beijing Normal University，Beijing 100875，China

Received:2023-10-30 Accepted:2024-01-15 Published:2024-02-01 Online:2024-03-05
Contact: Yu YANG,Li-An HOU
About author:houla@cae.cn
yangyu@bnu.edu.cn
Supported by:
the National Natural Science Foundation of China(51920105012)

Abstract

Abstract:

In recent years， due to the development of nuclear power and other industries， the pollution of heavy metals and radionuclides in water cannot be ignored， and the demand for clean water has become an important issue of global concern. Molybdenum disulfide （MoS₂） nanomaterials have attracted much attention in the fields of sterilization， hydrogen storage， water purification， etc. Membrane technology has become one of the options for the removal of heavy metals and radionuclides from water based on the advantages of simple operation and high efficiency. In this paper， the research progress of MoS₂-based nanomaterials and membranes in removing heavy metals and radionuclides from water is summarized， focusing on MoS₂ synthesis and modification methods， the main affect factors and mechanisms of heavy metals and radionuclides removal by MoS₂， the preparation of MoS₂-modified membranes， and the research progress on removing heavy metals and radionuclides from water by membrane technology， which aims at efficiently removing heavy metals and radionuclides.

Key words: MoS₂, Membrane, Heavy metal, Radionuclides, Water treatment

CLC Number:

O614.6

Yan-Jun ZHANG, Yu YANG, Li-An HOU. MoS₂ and Its Modified Membranes for Heavy Metals and Radionuclides Removal from Water[J]. Chinese Journal of Applied Chemistry, 2024, 41(2): 230-242.

Figures/Tables 6

References 79

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Heavy metals	Materials	Adsorption capacity/（mg·g^-1）	Adsorption mechanism	Ref.
Cd（Ⅱ）	MoS₂	14	Cd-S complexation	［28］
Hg（Ⅱ）	MoS₂	1 200	Redox reaction， complexation	［28］
Pb（Ⅱ）	MoS₂	366	Complexation	［28］
U（Ⅵ）	PVP/MoS₂	117.9	UO₂-S covalent bonds， PVP complexation	［31］
Ag（Ⅰ）	SA@MoS₂/rGO/MF	1 012.51	Redox reaction， coordination reaction	［32］
Ag（Ⅰ）	MoS₂	780	Ag-S complexation	［33］
Ag（Ⅰ）	MoS₂-W	598.8		［34］
Cu（Ⅱ）	1T-MoS₂	82.13		［35］
Pb（Ⅱ）	1T-MoS₂	147.09		［35］
Cu（Ⅱ）	MoS₂@2DMMT	65.75	Chemical adsorption	［36］
Cu（Ⅱ）	Fe₃O₄@MoS₂	198		［37］
Pb（Ⅱ）	Fe₃O₄@MoS₂	240.7		［37］
Hg（Ⅱ）	MoS₂/Fe₃O₄	～1 923.5	Hg-S complexation， electrostatic interactions	［38］
Pb（Ⅱ）	MoS₂B/CaCO₃/Alginate	833.3		［39］
Pb（Ⅱ）	MoS₂/PDA/MPS	371.7	Electrostatic interactions， complexation	［40］
U（Ⅵ）	MoS₂/BC	451.3	Chemical adsorption， electrostatic interactions， complexation et al.	［41］

Heavy metals	Materials	Adsorption capacity/（mg·g^-1）	Adsorption mechanism	Ref.
Cd（Ⅱ）	MoS₂	14	Cd-S complexation	［28］
Hg（Ⅱ）	MoS₂	1 200	Redox reaction， complexation	［28］
Pb（Ⅱ）	MoS₂	366	Complexation	［28］
U（Ⅵ）	PVP/MoS₂	117.9	UO₂-S covalent bonds， PVP complexation	［31］
Ag（Ⅰ）	SA@MoS₂/rGO/MF	1 012.51	Redox reaction， coordination reaction	［32］
Ag（Ⅰ）	MoS₂	780	Ag-S complexation	［33］
Ag（Ⅰ）	MoS₂-W	598.8		［34］
Cu（Ⅱ）	1T-MoS₂	82.13		［35］
Pb（Ⅱ）	1T-MoS₂	147.09		［35］
Cu（Ⅱ）	MoS₂@2DMMT	65.75	Chemical adsorption	［36］
Cu（Ⅱ）	Fe₃O₄@MoS₂	198		［37］
Pb（Ⅱ）	Fe₃O₄@MoS₂	240.7		［37］
Hg（Ⅱ）	MoS₂/Fe₃O₄	～1 923.5	Hg-S complexation， electrostatic interactions	［38］
Pb（Ⅱ）	MoS₂B/CaCO₃/Alginate	833.3		［39］
Pb（Ⅱ）	MoS₂/PDA/MPS	371.7	Electrostatic interactions， complexation	［40］
U（Ⅵ）	MoS₂/BC	451.3	Chemical adsorption， electrostatic interactions， complexation et al.	［41］

Heavy metals and radionuclides	Membrane ID	Removal/%	Removal mechanism	Ref.
Cd（Ⅱ）	MoS₂	~90	Adsorption	［44］
Pb（Ⅱ）	MoS₂	~100	Adsorption	［44］
Cr（Ⅵ）	Zn18-MoS₂@PVDF	＞90	Redox reaction and electrostatic interactions	［56］
Pb（Ⅱ）	SiO₂/TiO₂	＞90	Pb-S	［69］
Cr（Ⅵ）	MoS₂-PTCA	87	Redox reaction and adsorption	［73］
Hg（Ⅱ）	MoS₂-PTCA	85	Redox reaction and adsorption	［73］
Pb（Ⅱ）	MoS₂-PTCA	92	Adsorption	［73］
Cr（Ⅵ）	BC/MoS₂	88±3	Adsorption and photocatalytic	［74］
Pb（Ⅱ）	MC10	~98.5	Donnan effect	［75］
Co（Ⅱ）	MoS₂@NH₂-UiO-66	99.74	Ion exchange	［76］
Sr（Ⅱ）	MoS₂@NH₂-UiO-66	99.63	Ion exchange	［76］
Cs（Ⅰ）	MoS₂@NH₂-UiO-66	97.43	Ion exchange	［76］

Heavy metals and radionuclides	Membrane ID	Removal/%	Removal mechanism	Ref.
Cd（Ⅱ）	MoS₂	~90	Adsorption	［44］
Pb（Ⅱ）	MoS₂	~100	Adsorption	［44］
Cr（Ⅵ）	Zn18-MoS₂@PVDF	＞90	Redox reaction and electrostatic interactions	［56］
Pb（Ⅱ）	SiO₂/TiO₂	＞90	Pb-S	［69］
Cr（Ⅵ）	MoS₂-PTCA	87	Redox reaction and adsorption	［73］
Hg（Ⅱ）	MoS₂-PTCA	85	Redox reaction and adsorption	［73］
Pb（Ⅱ）	MoS₂-PTCA	92	Adsorption	［73］
Cr（Ⅵ）	BC/MoS₂	88±3	Adsorption and photocatalytic	［74］
Pb（Ⅱ）	MC10	~98.5	Donnan effect	［75］
Co（Ⅱ）	MoS₂@NH₂-UiO-66	99.74	Ion exchange	［76］
Sr（Ⅱ）	MoS₂@NH₂-UiO-66	99.63	Ion exchange	［76］
Cs（Ⅰ）	MoS₂@NH₂-UiO-66	97.43	Ion exchange	［76］

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MoS₂ and Its Modified Membranes for Heavy Metals and Radionuclides Removal from Water

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