Research Progress on Porous Titania Materials and Their Performances

doi:10.11944/j.issn.1000-0518.2018.09.180162

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (9): 1126-1132.DOI: 10.11944/j.issn.1000-0518.2018.09.180162

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Research Progress on Porous Titania Materials and Their Performances

SU Juan,CHEN Jiesheng()

School of Chemistry and Chemical Engineering,Shanghai Jiaotong University,Shanghai 200240,China

Received:2018-05-08 Accepted:2018-05-23 Published:2018-09-01 Online:2018-08-06
Contact: CHEN Jiesheng
Supported by:
Supported by the National Natural Science Foundation of China(No.21673140, No.21720102002, No.21331004)

Abstract

Abstract:

Porous titania(TiO₂) materials have important values and potentials in the fields of catalysis, energy, sensing, etc., due to their outstanding physical and chemical properties. In some applications associated with heterogeneous reactions, porous structures of TiO₂ are advantageous because they have rich channels for mass transfer and surface active sites with tunable pore sizes. Nowadays, porous TiO₂ materials are constantly developed and optimized in order to promote their industry applications. This review focuses on the research progress of porous TiO₂ and their applications in photocatalysis, photogenerated electron storage, and gas sensing, in which the performance regulated through the design of structures and defects are introduced and discussed. Our research work about a series of porous TiO₂ functional materials based on photochemical synthesis is specially introduced. Finally, the key issues and development prospects of porous TiO₂ and their performances are also discussed.

Key words: porous titania, photocatalysis, photogenerated electron storage, gas sensing, performances

SU Juan,CHEN Jiesheng. Research Progress on Porous Titania Materials and Their Performances[J]. Chinese Journal of Applied Chemistry, 2018, 35(9): 1126-1132.

References

[1]	Chen X,Mao S S.Titanium Dioxide Nanomaterials: Synthesis, Properties, Modifications, and Applications[J]. Chem Rev,2007,107(7):2891-2959.
[2]	Chen X,Liu L,Yu P Y,et al. Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals[J]. Science,2011,331(6018):746-750.
[3]	Su J,Chen J S.Synthetic Porous Materials Applied in Hydrogenation Reactions[J]. Micropor Mesopor Mater,2017,237:246-259.
[4]	Yang Y,Liang Y,Wang G,et al. Enhanced Gas-Sensing Properties of the Hierarchical TiO2 Hollow Microspheres with Exposed High-Energy {001} Crystal Facets[J]. ACS Appl Mater Interfaces,2015,7(44):24902-24908.
[5]	Du J,Lai X,Yang N,et al. Hierarchically Ordered Macro-Mesoporous TiO2-Graphene Composite Films:Improved Mass Transfer, Reduced Charge Recombination, and Their Enhanced Photocatalytic Activities[J]. ACS Nano,2011,5(1):590-596.
[6]	Seo M H,Yuasa M,Kida T,et al. Microstructure Control of TiO2 Nanotubular Films for Improved VOC Sensing[J]. Sens Actuators B,2011,154(2):251-256.
[7]	Gawri I,Ridhi R,Sing K P h,et al. Chemically Synthesized TiO2 and PANI/TiO2 Thin Films for Ethanol Sensing Applications[J]. Mater Res Express,2018,5(2):025303.
[8]	Pan J H,Zhang X,Du A J,et al. Self-Etching Reconstruction of Hierarchically Mesoporous F-TiO2 Hollow Microspherical Photocatalyst for Concurrent Membrane Water Purifications[J]. J Am Chem Soc,2008,130(34):11256-11257.
[9]	Zhang J,Xing Z,Cui J,et al. C,N Co-doped Porous TiO2 Hollow Sphere Visible Light Photocatalysts for Efficient Removal of Highly Toxic Phenolic Pollutants[J]. Dalton Trans,2018,47(14):4877-4884.
[10]	Li L,Bai S,Yin W J,et al. A Novel Etching and Reconstruction Route to Ultrathin Porous TiO2 Hollow Spheres for Enhanced Photocatalytic Hydrogen Evolution[J]. Int J Hydrogen Energy,2016,41(3):1627-1634.
[11]	Wei H,McMaster W A,Tan J Z Y,et al. Tricomponent Brookite/anatase TiO2/g-C3N4 Heterojunction in Mesoporous Hollow Microspheres for Enhanced Visible-light Photocatalysis[J]. J Mater Chem A,2018,6(16):7236-7245.
[12]	Pang L,Wang X,Tang X.Enhanced Photocatalytic Performance of Porous TiO2 Nanobelts with Phase Junctions[J]. Solid State Sci,2015,39:29-33.
[13]	Yao Y C,Dai X R,Hu X Y,et al. Synthesis of Ag-decorated Porous TiO2 Nanowires Through a Sunlight Induced Reduction Method and Its Enhanced Photocatalytic Activity[J]. Appl Surf Sci,2016,387:469-476.
[14]	Petkovich N D,Stein A.Controlling Macro- and Mesostructures with Hierarchical Porosity Through Combined Hard and Soft Templating[J]. Chem Soc Rev,2013,42(9):3721-3739.
[15]	Song Y,Li N,Chen D,et al. N-Doped and CdSe-Sensitized 3D-Ordered TiO2 Inverse Opal Films for Synergistically Enhanced Photocatalytic Performance[J]. ACS Sustainable Chem Eng,2018,6(3):4000-4007.
[16]	Purbia R,Borah R,Paria S.Carbon-Doped Mesoporous Anatase TiO2 Multi-Tubes Nanostructures for Highly Improved Visible Light Photocatalytic Activity[J]. Inorg Chem,2017,56(16):10107-10116.
[17]	Zhang Z,Zuo F,Feng P.TiO2 Hard Template Synthesis of Crystalline Mesoporous Anatase TiO2 for Photocatalytic Hydrogen Evolution[J]. J Mater Chem,2010,20:2206-2212.
[18]	Wang H,Liu H,Wang S,et al. Influence of Tunable Pore Size on Photocatalytic and Photoelectrochemical Performances of Hierarchical Porous TiO2/C Nanocomposites Synthesized via Dual-Templating[J]. Appl Catal B:Environ,2018,224:341-349.
[19]	Liu B,Peng L.Facile Formation of Mixed Phase Porous TiO2 Nanotubes and Enhanced Visible-light Photocatalytic Activity[J]. J Alloy Compd,2013,571:145-152.
[20]	Zou X X,Li G D,Chen J S,et al. Light-induced Formation of Porous TiO2 with Superior Electron-storing Capacity[J]. Chem Commun,2010,46(12):2112-2114.
[21]	Su J,Zou X X,Chen J S,et al. Porous Vanadium-doped Titania with Active Hydrogen:A Renewable Reductant for Chemoselective Hydrogenation of Nitroarenes under Ambient Conditions[J]. Chem Commun,2012,48(72):9032-9034.
[22]	Jia D,Qi Z,Li X,et al. 3D Hierarchical Macro/mesoporous TiO2 with Nanoporous or Nanotubular Structures and Their Core/shell Composites Achieved by Anodization[J]. CrystEngComm,2017,19(18):2509-2516.
[23]	Su J,Zou X X,Chen J S,et al. Room-temperature Spontaneous Crystallization of Porous Amorphous Titania for High-surface-area Anatase Photocatalyst[J]. Chem Commun,2013,49(74):8217-8219.
[24]	Li Y N,Chen Z Y,Wang M Q,et al. Interface Engineered Construction of Porous g-C3N4/TiO2 Heterostructure for Enhanced Photocatalysis of Organic Pollutants[J]. Appl Surf Sci,2018,440:229-236.
[25]	Su J,Zou X X,Chen J S.Self-modification of Titanium Dioxide Materials by Ti3+ and/or Oxygen Vacancies:New Insights into Defect Chemistry of Metal Oxides[J]. RSC Adv,2014,4(27):13979-13988.
[26]	Zuo F,Wang L,Wu T,et al. Self-Doped Ti3+ Enhanced Photocatalyst for Hydrogen Production under Visible Light[J]. J Am Chem Soc,2010,132(34):11856-11857.
[27]	Zou X X,Chen J S,Feng P Y,et al. Facile Synthesis of Thermal- and Photostable Titania with Paramagnetic Oxygen Vacancies for Visible-Light Photocatalysis[J]. Chem Eur J,2013,19(8):2866-2873.
[28]	Kongkanand A,Kamat P V.Electron Storage in Single Wall Carbon Nanotubes. Fermi Level Equilibration in Semiconductor SWCNT Suspensions[J]. ACS Nano,2007,1(1):13-21.
[29]	Kuznetsov A I,Kameneva O,Alexandrov A,et al. Chemical Activity of Photoinduced Ti3+ Centers in Titanium Oxide Gels[J]. J Phys Chem B,2006,110(1):435-441.
[30]	Kameneva O,Kuznestov A I,Smirnova L A,et al. New Photoactive Hybrid Organic Inorganic Materials Based on Titanium-oxo-PHEMA Nanocomposites Exhibiting Mixed Valence Properties[J]. J Mater Chem,2005,15(33):3380-3383.
[31]	Kuznetsov A I,Kameneva O,Bityurin N,et al. Laser-induced Photopatterning of Organic Inorganic TiO2-based Hybrid Materials with Tunable Interfacial Electron Transfer[J]. Phys Chem Chem Phys,2009,11(8):1248-1257.
[32]	Schrauben J N,Hayoun R,Valdez C N,et al. Titanium and Zinc Oxide Nanoparticles are Proton-Coupled Electron Transfer Agents[J]. Science,2012,336(6086):1298-1301.
[33]	Su J,Zou X X,Chen J S,et al. Accelerated Room-temperature Crystallization of Ultrahigh-surface-area Porous Anatase Titania by Storing Photogenerated Electrons[J]. Chem Commun,2017,53(10):1619-1621.
[34]	Li X,Chen N,Lin S,et al. NiO-wrapped Mesoporous TiO2 Microspheres Based Selective Ammonia Sensor at Room Temperature[J]. Sens Actuators B,2015,209:729-734.
[35]	Su J,Zou X X,Chen J S,et al. Porous Titania with Heavily Self-doped Ti3+ for Specific Sensing of CO at Room Temperature[J]. Inorg Chem,2013,52(10):5924-5930.
[36]	Lira E,Wendt S,Huo P,et al. The Importance of Bulk Ti3+ Defects in the Oxygen Chemistry on Titania Surfaces[J]. J Am Chem Soc,2011,133(17):6529-6532.
[37]	Zou X X,Li G D,Chen J S,et al. Experimental Validation of the Importance of Thermally Stable Bulk ReductionStates in TiO2 for Gas Sensor Applications[J]. Acta Chim Sin,2012,70:1477-1482.

Research Progress on Porous Titania Materials and Their Performances

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