Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials

doi:10.11944/j.issn.1000-0518.2018.01.170344

Chinese Journal of Applied Chemistry ›› 2018, Vol. 35 ›› Issue (1): 53-59.DOI: 10.11944/j.issn.1000-0518.2018.01.170344

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Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials

SUN Qi^a^b,WANG Liqiu^a^*(),LIU Yang^a,GUO Chenxiao^a,WANG Pengjun^a,LIU Xuelong^a,ZHANG Xiaobo^a,ZHENG Lihui^a,LIU Liping^c

^aCollege of Environmental and Chemical Engineering,Yanshan University,Qinhuangdao,Hebei 066004,China
^bJiangxi Kingan Hi-Tech Co.,Ltd. Nanchang 330508,China
^cQiqihar Education and Teaching Research Institute,Qiqihar,Heilongjiang 161005,China

Received:2017-09-19 Accepted:2017-10-30 Published:2018-01-03 Online:2018-01-03
Contact: WANG Liqiu
Supported by:
Supported by Hebei Natural Science Foundation(No.B2015203259)

Abstract

Abstract:

Near-infrared fluorescence squaraine/polyvinyl alcohol(PVA) binary and squaraine/hydrophilic graphene/PVA ternary polymers with stronger fluorescence(660~665 nm) intensity, photostability and thermostability were designed and synthesized from a squaraine dye, water soluble graphene and PVA. Compared to those in water, the maximum UV-Vis absorption and fluorescence wavelengths of the squaraine in PVA showed red shifts, and the fluorescence intensity and photostability were significantly enhanced. The presence of the graphene improved the photostability and thermostability of the material.

Key words: near infrared fluorescence polymer materials, polyvinyl alcohol, modification and synthesis, squaraine dye, hydrophilic grapheme

SUN Qi, WANG Liqiu, LIU Yang, GUO Chenxiao, WANG Pengjun, LIU Xuelong, ZHANG Xiaobo, ZHENG Lihui, LIU Liping. Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials[J]. Chinese Journal of Applied Chemistry, 2018, 35(1): 53-59.

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Preparation and Properties of Near Infrared Polyvinyl Alcohol Fluorescent Polymer Materials

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