Phosphate Removal by Using Shield Residues/Carbon Composite Ceramsite

doi:10.11944/j.issn.1000-0518.2017.02.160176

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (2): 211-219.DOI: 10.11944/j.issn.1000-0518.2017.02.160176

• Full Papers • Previous Articles Next Articles

Phosphate Removal by Using Shield Residues/Carbon Composite Ceramsite

XIE Fezhi^a^b^*(),LI Haibin^a^c,LI Guolian^b^d,CHEN Jianli^a^c,YANG Wen^a^c,WANG Xuechun^a^c,HU Tingting^a^c,SHENG Dandan^a^c,XIE Zhiyong^a^c

^aSchool of Materials and Chemical Engineering,Anhui Jianzhu University,Hefei 230601,China
^bAnhui Key Laboratory of Water Pollution Control and Wastewater Resource,Anhui Jianzhu University,Hefei 230601,China
^cAnhui Key Laboratory of Advanced Building Materials,Anhui Jianzhu University,Hefei 230601,China
^dSchool of Environment and Energy Engineering,Anhui Jianzhu University,Hefei 230601,China

Received:2016-04-26 Accepted:2016-07-08 Published:2017-01-18 Online:2017-01-18
Contact: XIE Fezhi
Supported by:
Supported by the National Natural Science Foundation of China(No.21107001), the Natural Science Foundation of Anhui Province, China(No.1608085MB43), the Natural Science Foundation of Education Department of Anhui Province(No.KJ2016A154), the Outstanding Youth Elite Support Program in Universities of Anhui Province(No.2014-5)

Abstract

Abstract:

Composite ceramsite was prepared by sintering solid waste residue of shield residues, powdered rice straw and magnesium oxide. The effects of pH, sorption time and temperature were investigated. The results show that the optimal sintering temperature of the composite ceramsite is 700 ℃ with the mass ratio of shield residue to powdered rice straw and to magnesium oxide as 7:2:1. The optimum adsorption pH is 6.3, and phosphate can reach adsorption equilibrium within 12 hours. The Lagergren pseudo second order kinetics and the Temkin isotherm model fit the experimental data well. The adsorption capacity increases with increasing the sorption temperature, and the maximum adsorption of ceramsite is 12.76 mg/g at 40 ℃. The adsorption is confirmed as a nonspontaneous endothermic process according to the results of ΔH=5.64 kJ/mol>0, ΔS=8.00 J/(K·mol)>0, ΔG=3.16 kJ/mol>0. Meanwhile, the adsorbed phosphate on ceramsite can be recovered by using 2.0 mol/L NaOH.

Key words: shield residue, carbon, ceramsite, phosphate, adsorption

XIE Fezhi, LI Haibin, LI Guolian, CHEN Jianli, YANG Wen, WANG Xuechun, HU Tingting, SHENG Dandan, XIE Zhiyong. Phosphate Removal by Using Shield Residues/Carbon Composite Ceramsite[J]. Chinese Journal of Applied Chemistry, 2017, 34(2): 211-219.

References

[1]	Welivita I,Wattage P,Gunawardena P. Review of Household Solid Waste Charges for Developing Countries-A Focus on Quantity-based Charge Methods[J]. Waste Manage,2015,46:637-645.
[2]	Khan D,Kumar A,Samadder S R. Impact of Socioeconomic Status on Municipal Solid Waste Generation Rate[J]. Waste Manage,2016,49:15-25.
[3]	Yang Y,Inamoi Y,Ojima H,et al.Development of an Advanced Biological Treatment System Applied to the Removal of Nitrogen and Phosphorus Using the Sludge Ceramics[J]. Water Res,2005,39(20):4859-4868.
[4]	Yue Q,Zhao Y,Li Q,et al.Research on the Characteristics of Red Mud Granular Adsorbents(RMGA) for Phosphate Removal[J]. J Hazard Mater,2010,176(1):741-748.
[5]	LUO Peicong,LIU Yi,LUO Jun,et al.Preparation of Fly Ash Ceramsite with High Phosphorus Removal Efficiency Used for Filter Materials[J]. Chinese J Environ Eng,2012,6(11):3849-3854(in Chinese). 罗沛聪,刘怡,罗隽,等.用于水处理的高效除磷型粉煤灰陶粒滤料的研制[J].环境工程学报,2012,6(11):3849-3854.
[6]	JIANG Li,CHEN Jianyu,LI Xiaoming,et al.Adsorption of Phosphate from Wastewater by Fly Ash Ceramsite[J]. Acta Sci Circumst,2011,31(7):1413-1420(in Chinese). 蒋丽,谌建宇,李小明,等. 粉煤灰陶粒对废水中磷酸盐的吸附试验研究[J]. 环境科学学报,2011,31(7):1413-1420.
[7]	ZHU Hong,CHANG Zhizhou,HUANG Hongying,et al.High Temperature Burning of Straw Ash P, K Nutrient Change[J]. J Plant Nutr Fertil,2007,13(6):1197-1201(in Chinese). 朱红,常志州,黄红英,等. 高温焚烧对秸秆灰渣磷,钾养分变化的影响[J]. 植物营养与肥料学报,2007,13(6):1197-1201.
[8]	Xie F Z,Wu F C,Liu G J,et al.Removal of Phosphate from Eutrophic Lakes Through Adsorption by in Situ Formation of Magnesium Hydroxide from Diatomite[J]. Environ Sci Technol,2013,48(1):582-590.
[9]	BAI Zhaoxing,CAO Jianfeng,LIN Pengyun,et al.Straw Biomass Combustion Dynamics Study[J]. Energy Res Inf,2009,25(3):130-137(in Chinese). 白兆兴,曹建峰,林鹏云,等. 秸秆类生物质燃烧动力学特性实验研究[J]. 能源研究与信息,2009,25(3):130-137.
[10]	LIU Mingwei,TANG Jinhua,XU Guoren. Content of MgO Style Changes Affect the Performance of Sludge Ceramsite[J]. J Heilongjiang Univ(Nat Sci,) 2013,30(5):628-634(in Chinese). 刘明伟,唐金花,许国仁.MgO含量变化对污泥陶粒性能的影响[J].黑龙江大学学报(自然科学版),2013,30(5):628-634.
[11]	SU Li,LI Huan,YU Jingkun. Magnesium Oxide Activity Relationship with Its Microstructure[J]. J Mater Metall,2007,5(4):308-311(in Chinese). 苏莉,李环,于景坤. 氧化镁活性与其微观结构的关系[J]. 材料与冶金学报,2007,5(4):308-311.
[12]	Qin J,Cui C,Cui X Y,et al.Preparation and Characterization of Ceramsite From Lime Mud and Coal Fly Ash[J]. Construct Build Mater,2015,95(1):10-17.
[13]	PENG Weihua,GUI Herong. Fiber Ceramsite as the Filler and Its Rapid Biofilm Culturing in Biological Filter[J]. Technol Water Treat,2012,38(8):76-79(in Chinese). 彭位华,桂和荣. 纤维陶粒作为填料在生物滤池中的快速挂膜[J]. 水处理技术,2012,38(8):76-79.
[14]	Apak R,Tutem E,Hugul M,et al.Heavy Metal Cation Retention by Unconventional Sorbents(Red Muds and Fly Ashes)[J]. Water Res,1998,32(2): 430-440.
[15]	Bothe J V,Brown P W. Arsenic Immobilization by Calcium Arsenate Formation[J]. Environ Sci Technol,1999,33(21):3806-3811.
[16]	Zhou J B,Yang S L,Yu J G. Facile Fabrication of Mesoporous MgO Microspheres and Their Enhanced Adsorption Performance from Aqueous Solutions[J]. Colloids Surf A,2011,379(1):102-108.
[17]	JIN Shiwei,ZAHO Shurong,ZHOU Wei. Magnesium Hydroxide Containing Phosphorus Wastewater Treatment[J]. J Wuhan Univ Eng,2012,34(8):19-23(in Chinese). 金士威,赵淑荣,周威. 氢氧化镁处理含磷废水[J]. 武汉工程大学学报,2012,34(8):19-23.
[18]	LIU Xiao,LI Xuelian,CAO Guoping. Adsorption Effect of Steel Slag Haydite on Phosphorus in Wastewater[J]. Ind Water Treat,2014,34(1):18-21(in Chinese). 刘晓,李学莲,曹国凭. 钢渣陶粒对废水中磷的吸附特性[J]. 工业水处理,2014,34(1):18-21.
[19]	Yu Y,Chen J P. Key Factors for Optimum Performance in Phosphate Removal from Contaminated Water by a Fe-Mg-La tri-Metal Composite Sorbent[J]. J Colloid Interface Sci,2015,445:303-311.
[20]	ZHAO Guiyu,ZHOU Qi. Shale Ceramsite to the Adsorption and the Dynamics of Phosphorus in Water[J]. Environ Pollut Control,2007,3(29):182-185(in Chinese). 赵桂瑜,周琪. 页岩陶粒对水体中磷的吸附作用及动力学[J]. 环境污染与防,2007,3(29):182-185.
[21]	Oladoja N A,Ololade I A,Olaseni S E,et al.Synthesis of Nano Calcium Oxide from a Gastropod Shell and the Performance Evaluation for Cr(Ⅵ) Removal from Aqua System[J]. Ind Eng Chem Res,2011,51(2):639-648.
[22]	Ünlu N,Ersoz M. Adsorption Characteristics of Heavy Metal Ions onto a Low Cost Biopolymeric Sorbent From Aqueous Solutions[J]. J Hazard Mater,2006,136(2):272-280.
[23]	DANG Zhi,YU Hong,HUANG Weilin,et al.Research Progress of Soil/Sediment Adsorption Mechanism of Organic Pollutants[J]. Chemistry,2001,64(2):81-85(in Chinese). 党志,于虹,黄伟林,等. 土壤/沉积物吸附有机污染物机理研究的进展[J]. 化学通报,2001,64(2):81-85.
[24]	SHU Yuehong,JIA Xiaoshan. CTMAB-bentonite Adsorption Mechanism of Chlorobenzene Compounds in Water-The Adsorption Kinetics and Thermodynamics[J]. J Environ Sci,2005,25(11):1530-1536(in Chinese). 舒月红,贾晓珊. CTMAB-膨润土从水中吸附氯苯类化合物的机理—吸附动力学与热力学[J]. 环境科学学报,2005,25(11):1530-1536.
[25]	ZHOU Weifeng. Three Kinds of Typical Soil Comparative Study on the Adsorption Mechanism of Polychlorinated Biphenyls[D]. Zhejiang University,2011(in Chinese). 周蔚凤. 三种代表性土壤对多氯联苯的吸附机理比较研究[D]. 浙江:浙江大学,2011.
[26]	KANG Lu,WU Jinggui,ZAHNG Jinjing,et al.Soil and Soil Minerals to the Class of Humic Acid Adsorption Desorption and Influencing Factors of Research[J]. J Environ Sci,2013,33(5):1332-1340(in Chinese). 康露,吴景贵,张晋京,等. 土壤及土壤矿物对类胡敏酸的吸附解吸及其影响因素研究[J]. 环境科学学报,2013,33(5):1332-1340.
[27]	Li J,Werth C J. Modeling Sorption Isotherms of Volatile Organic Chemical Mixtures in Model and Natural Solids[J]. Environ Toxicol Chem,2002,21(7):1377-1383.
[28]	Kim B T,Lee H K,Moon H,et al.Adsorption of Radionuclides from Aqueous Solutions by Inorganic Adsorbents[J]. Sep Sci Technol,1995,30(16):3165-3182.
[29]	DING Wenming,HUANG Xia. Progress of Studies on Phosphorus Removal From Wastewater by Adsorbents[J]. Tech Equip Environ Pollut Control,2002,3(10):23-27(in Chinese). 丁文明,黄霞. 废水吸附法除磷的研究进展[J]. 环境污染治理技术与设备,2002,3(10):23-27.
[30]	Cheng J,Li Y J,Zhang B,et al.Comparison of Quartz Sand, Anthracite, Shale and Biological Ceramsite for Adsorptive Removal of Phosphorus from Aqueous Solution[J]. J Environ Sci,2014,26(2):466-477.
[31]	Dubinin M M. The Potential Theory of Adsorption of Gases and Vapors for Adsorbents with Energetically Nonuniform Surfaces[J]. Chem Rev,1960,60(2):235-241.
[32]	Gen -Fuhrman H,Tjell J C,McConchie D. Adsorption of Arsenic from Water Using Activated Neutralized Red Mud[J]. Environ Sci Technol,2004,38(8):2428-2434.
[33]	YUE Qinyan,YUAN Aijuan,LI Qian,et al.Decoloration of Reactive Turquoise Blue by Acidified Sludge-Bentonite Granule[J]. Environ Sci,2009,30(5):1447-1492(in Chinese). 岳钦艳,原爱娟,李倩,等. 酸化污泥膨润土颗粒对染料活性翠蓝的脱色研究[J]. 环境科学,2009,30(5):1447-1492.

Phosphate Removal by Using Shield Residues/Carbon Composite Ceramsite

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jia-Cheng ZHOU, Dong-Dong WANG, Yun-Bao GAO, Jing JIN, Wei JIANG. Rheological Properties and Bonding Properties of Modified Poly（Propylene Carbonate） Pressure-sensitive Adhesive [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 871-878.
[2]	Ning YUAN, Jie MA, Jin-Ling ZHANG, Jian-Sheng ZHANG. Preparation of PCN-6（M） Bimetallic Organic Framework Materials by Steam-assisted Method and Their CO₂ and CH₄ Adsorption Performance [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 896-903.
[3]	Feng ZHU, Xiao-Lian PENG, Wen-Bin ZHANG. Research Progress in the Effects of Proton Acceptor/Donor on Electrocatalytic Reactions [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 666-680.
[4]	Yuan-Hua ZHANG, Sheng-Ran LI, Xi-Fei YU. Fluoride-Functionalized Choline Phosphate Liposomes for Oral Insulin Administration [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 730-742.
[5]	Chen-Li HAO, Qing-Wei DING, Shi-Chang JIA, Yang-Bo MAO, Song-Bai WANG, Jun MA. Adsorption of Methylene Blue on Titanate Nanotubes Modified with Lipoic Acid [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 749-757.
[6]	Yue-Xia ZHANG, Xiao-Peng FAN, Yu-Juan CAO, Xin-Tong YANG, Zhong-Ping LI, Zhen-Hua YANG, Chuan DONG. Synthesis of Oil-soluble Carbon Quantum Dots by Pyrolysis Method for the Detection of Oxytetracycline [J]. Chinese Journal of Applied Chemistry, 2023, 40(4): 509-517.
[7]	Yu-Xi WANG, Dong WANG, Chun-Xia TANG, Chang-Sen DU, Shu-Qin FENG, Shao-Hai FU. Preparation and Properties of Ethylene Glycol Carbon Black Paste [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 389-396.
[8]	Bo XIONG, Tai-Hua LI, Wu-Ping ZHOU, Chang-Yu LIU, Xiao-Long XU. Preparation of Cu₂O/CuO-g-C₃N₄ Adsorbent by One-step Thermal Polymerization and Adsorption Properties for Methyl Orange [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 420-429.
[9]	Qin ZHANG, Wen-Bin LIU, Li-Jiao FAN, Yu-Ming XIE, Guo-Lin HUANG. Research Progress in the Preparation of Functionalized Mesoporous Silica and Its Application in Adsorption and Separation of Uranium from Water [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 169-187.
[10]	Rui-Zhe WANG, Guang-Qi HU, Wei-Hao YE, Chao-Fan HU, Jian-Le ZHUANG, Bing-Fu LEI, Wei LI, Ying-Liang LIU. Hydrothermal Preparation and Application of Oil-soluble Carbon Dots with High Ultraviolet-short-wave Blue Light Shielding [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 59-68.
[11]	Zhen-Hua YANG, Xuan-Sen SUN, Yue-Xia ZHANG, Yu-Juan CAO, Qi-Qi ZHANG, Qiao-Zhi GUO, Xiao-Peng FAN, Zhong-Ping LI, Chuan DONG. Preparation of Nitrogen Sulfur Co⁃doped Carbon Dots with Nitrogen Sulfur and the Application for Detection of Oxytetracycline in Milk [J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1382-1390.
[12]	Yue-Hua ZHAO, Da-Peng WANG. Coadsorption Kinetics of Amino‑Functionalized Graphene Oxide and Fatty Acids at the Water/Oil Interface [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1274-1284.
[13]	Lian-Bo TANG, Da-You FU, Qi CHEN, Yang-Run FENG, Ya-Lin XIONG, Zhu-Qing WANG. Enhanced Gas⁃Liquid Chemiluminescence by Carbon Dots for Determination of Carbon Dioxide [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1294-1302.
[14]	Zhi-Qiang QIAO, De-Qiang JI, Peng WANG, Ying-Ming HE, Zhi-Da LI, De-Bin JI, Hong-Jun WU. Progress in Preparation of Carbon Materials by Electrochemical Reduction of Carbon Dioxide in Molten Salt [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1026-1038.
[15]	Xiao-Mei WANG, Jiang-Fei GUO, Li-Zhi WANG, Jian-Han HUANG. Porphyrin⁃Based Hyper⁃cross⁃Linked Polymer： Preparation and Adsorption of Carbon Dioxide and Hg（Ⅱ） Ion [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1083-1089.