Synthesis of Morphology-controllable Porphyrin Materials and Their Photoelectric Properties

doi:10.11944/j.issn.1000-0518.2016.03.150217

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (3): 307-312.DOI: 10.11944/j.issn.1000-0518.2016.03.150217

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Synthesis of Morphology-controllable Porphyrin Materials and Their Photoelectric Properties

YANG Jiandong^a^b,MA Rong^a,YAN Xiang^a,WANG douliu^a,LU Xiaoquan^b^*()

^aDepartment of Biology & Chemistry,Longnan Normal College,Chengxian,Gansu 742500,China
^bKey Lab of Bioelectrochemisty & Environmental analysis of Gansu Province
Northwest Normal of University,Lanzhou 730070,China

Received:2015-06-29 Accepted:2015-12-03 Published:2016-03-02 Online:2016-03-02
Contact: LU Xiaoquan
Supported by:
Supported by the National Natural Science Fundation of China(No.21175108), the Natural Science Fundation of Gansu Province(No.1308RJZK171), the Research Foundation for High Education of Gansu Province(No.2013B132)

Abstract

Abstract:

Various porphyrin-containing nanostructures were facilely synthesized by self-assembly technology via modulations of the pH of mixture solution. At low pH, one-dimensional bar is formed, and at high pH, two-dimensional lamellar structure appears. These nanostructures were analyzed by UV-Vis, IR and XRD. One dimensional J-aggregates is formed at low pH through the packing of porphyrin molecules by π-π, and electrostatic interactions. As the pH increases, hydrogen bond plays a key role to switch the porphyrin aggregates into two-dimensional sheets. Photoelectric property test shows a good response of the porphyrin nano-rods to the visible light. This kind of porphyrin nano materials with photoelectric response is expected to be a photoelectric element in electronic devices.

Key words: preparing method, porphyrin nanomaterials, photoelectric properties

YANG Jiandong, MA Rong, YAN Xiang, WANG douliu, LU Xiaoquan. Synthesis of Morphology-controllable Porphyrin Materials and Their Photoelectric Properties[J]. Chinese Journal of Applied Chemistry, 2016, 33(3): 307-312.

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Synthesis of Morphology-controllable Porphyrin Materials and Their Photoelectric Properties

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