Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution

doi:10.11944/j.issn.1000-0518.2015.09.150111

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (9): 1061-1069.DOI: 10.11944/j.issn.1000-0518.2015.09.150111

• Full Papers • Previous Articles Next Articles

Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution

LIU Ru^a,LI Haiping^a,HOU Wanguo^a^b^*()

^aNational Engineering Research Center for Colloidal Materials,Shandong Univerisy,Ji'nan 250100,China
^bKey Laboratory of Colloid and Interface Chemistry(Ministry of Education),Shandong University,Ji'nan 250100,China

Received:2015-03-23 Accepted:2015-05-17 Published:2015-08-31 Online:2015-08-31
Contact: HOU Wanguo
Supported by:
Supported by the National Natural Science Foundation of China(No.21173135, No.21403128)

Abstract

Abstract:

A water-soluble weakly crosslinked xanthan gum(XG) was synthesized using sodium trimetaphosphate(STMP) as a crosslinker, and the synthesis conditions were optimized based on the viscosity of the STMP crosslinked XG(denoted as SP-c-XG) solutions. Effects of electrolyte(NaCl and CaCl₂) mass fraction(0~5.0%), pH(2~11), and temperature(20~70 ℃) on the rheological properties of the SP-c-XG solutions were investigated and compared with those of XG solutions. The results show that, under the studied conditions, the rheological curves of both SP-c-XG and XG solutions are pseudoplastic and can be described by Herschel-Bulkley model. The yield stress, apparent viscosity and dynamic moduli of the SP-c-XG and XG solutions initially decrease and then increase with increasing electrolyte concentration, but they initially increase and then decrease with increasing pH. Increasing temperature results in a decrease in these rheological parameter values for both SP-c-XG and XG solutions. The rheological properties of the SP-c-XG solution are similar to those of the XG solution. However, compared with the XG solution, the SP-c-XG solution exhibits higher yield stress and apparent viscosity, especially stronger elasticity and temperature resistance, indicating its use potential in enhanced oil recovery.

Key words: xanthan gum, sodium trimetaphosphate, crosslink, rheology, temperature resistance

LIU Ru,LI Haiping,HOU Wanguo. Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution[J]. Chinese Journal of Applied Chemistry, 2015, 32(9): 1061-1069.

References

[1]	Pelletier E,Viebke C,Meadows J,et al.A Rheological Study of the Order-disorder Conformational Transition of Xanthan Gum[J]. Biopolymers,2001,59(5):339-346.
[2]	Pooja D,Panyaram S,Kulhari H,et al.Xanthan Gum Stabilized Gold Nanoparticles:Characterization, Biocompatibility, Stability and Cytotoxicity[J]. Carbohydr Polym,2014,110:1-9.
[3]	Kumar R,Srivastava A,Behari K. Graft Copolymerization of Methacrylic Acid onto Xanthan Gum by Fe2+/H2O2 Redox Initiator[J]. J Appl Polym Sci,2007,105(4):1922-1929.
[4]	Becker A,Katzen F,P hler A,et al. Xanthan Gum Biosynthesis and Application:A Biochemical/genetic Perspective[J]. Appl Microbiol Biotechnol,1998,50(2):145-152.
[5]	ZHANG Xi,CAO Ya. Application and Prospect of Polymer Materials for Oil Production Engineering[J]. Oilfield Chem,2003,20(1):94-98(in Chinese). 张熙,曹亚. 高分子材料在采油工程中的应用与展望[J]. 油田化学,2003,20(1):94-98.
[6]	YAN Xin,HUANG Lixian. Laboratory Preparation of Heat Resistant Xanthan/chromium Gelling Fluid as Profile Modifying/water Plugging Agent[J]. Oilfield Chem,2002,19(2):131-133(in Chinese). 颜鑫,黄丽仙. 耐温黄胞胶铬冻胶调堵剂室内研制[J]. 油田化学,2002,19(2):131-133.
[7]	Sand A,Yadav M,Behari K. Graft Copolymerization of 2-Acrylamidoglycolic Acid on to Xanthan Gum and Study of Its Physicochemical Properties[J]. Carbohydr Polym,2010,81(3):626-632.
[8]	Hamcerencu M,Desbrieres J,Popa M,et al.Stimuli-sensitive Xanthan Derivatives/N-Isopropylacrylamide Hydrogels:Influence of Cross-linking Agent on Interpenetrating Polymer Network Properties[J]. Biomacromolecules,2009,10(7):1911-1922.
[9]	Pandey P K,Banerjee J,Taunk K,et al.Graft Copolymerization of Acrylic Acid onto Xanthum Gum Using a Potassium Monopersulfate/Fe2+ Redox Pair[J]. J Appl Polym Sci,2002,89:1341-1346.
[10]	Kumar A,Singh K,Ahuja M. Xanthan-g-poly (acrylamide):Microwave-assisted Synthesis, Characterization and in Vitro Release Behavior[J]. Carbohydr Polym,2009,76(2):261-267.
[11]	Li Y F,Ha Y M,Tao L R,et al.Preparation of Xanthan Gum-g-N-vinylpyrrolidone by Radiation and Adsorption Property of Phenol and Polyphenol[J]. Adv Mater Res,2011,236:2694-2700.
[12]	Pandey S,Mishra S B. Graft Copolymerization of Ethylacrylate onto Xanthan Gum, Using Potassium Peroxydisulfate as an Initiator[J]. Int J Biol Macromol,2011,49(4):527-535.
[13]	Dumitriu S,Dumitriu M,Teaca G. Bioactive Polymers 65-studies of Cross-linked Xanthan Hydrogels as Supports in Drug Retardation[J]. Clin Mater,1990,6(3):265-276.
[14]	Bejenariu A,Popa M,Dulong V,et al.Trisodium Trimetaphosphate Crosslinked Xanthan Networks:Synthesis, Swelling, Loading and Releasing Behaviour[J]. Polym Bull,2009,62(4):525-538.
[15]	Bala R,Khanna S,Pawar P. Polymers in Fast Disintegrating Tablets-a review[J]. Asian J Pharm Clin Res,2012,5(2):8-14.
[16]	Kasemsuwan T,Bailey T,Jane J. Preparation of Clear Noodles with Mixtures of Tapioca and High-amylose Starches[J]. Carbohydr Polym,1998,36(4):301-312.
[17]	Mocanu G,Mihai D,Picton L,et al.Associative Pullulan Gels and Their Interaction with Biological Active Substances[J]. J Controlled Release,2002,83(1):41-51.
[18]	Shalviri A,Liu Q,Abdekhodaie M J,et al.Novel Modified Starch-xanthan Gum Hydrogels for Controlled Drug Delivery:Synthesis and Characterization[J]. Carbohydr Polym,2010,79(4):898-907.
[19]	Gliko-Kabir I,Yagen B,Baluom M,et al.Phosphated Crosslinked Guar for Colon-specific Drug Delivery:Ⅱ.In Vitro and in Vivo Evaluation in the Rat[J]. J Controlled Release,2000,63(1):129-134.
[20]	Launer H F,Tomimatsu Y. Alkali Sensitivity of Polysaccharides:Periodate Starches, Periodate Dextran and a Polygalacturonide1[J]. J Org Chem,1961,26(2):541-545.
[21]	Mundargi R C,Patil S A,Aminabhavi T M. Evaluation of Acrylamide-grafted-xanthan Gum Copolymer Matrix Tablets for Oral Controlled Delivery of Antihypertensive Drugs[J]. Carbohydr Polym,2007,69(1):130-141.
[22]	Su L,Ji W K,Lan W Z,et al.Chemical Modification of Xanthan Gum to Increase Dissolution Rate[J]. Carbohydr Polym,2003,53(4):497-499.
[23]	Jampala S N,Manolache S,Gunasekaran S,et al.Plasma-enhanced Modification of Xanthan Gum and Its Effect on Rheological Properties[J]. J Agric Food Chem,2005,53(9):3618-3625.
[24]	Marlier J F. Heavy-atom Isotope Effects on the Alkaline Hydrolysis of Methyl Formate:the Role of Hydroxide Ion in Ester Hydrolysis[J]. J Am Chem Soc,1993,115(14):5953-5956.
[25]	Sang Y,Prakash O,Seib P A. Characterization of Phosphorylated Cross-linked Resistant Starch by 31P Nuclear Magnetic Resonance(31P NMR) Spectroscopy[J]. Carbohydr Polym,2007,67(2):201-212.
[26]	Smith I H,Symes K C,Lawson C J,et al.Influence of the Pyruvate Content of Xanthan on Macromolecular Association in Solution[J]. Int J Biol Macromol,1981,3(2):129-134.
[27]	Goh K K T,Haisman D R,Singh H. Characterisation of a High Acyl Gellan Polysaccharide Using Light Scattering and Rheological Techniques[J]. Food Hydrocolloids,2006,20(2):176-183.
[28]	Izawa H,Kadokawa J. Preparation and Characterizations of Functional Ionic Liquid-gel and Hydrogel Materials of Xanthan Gum[J]. J Mater Chem,2010,20(25):5235-5241.
[29]	Lee H K,Kang W H. Dissolution Properties of Phosphate Glasses with Trace Elements[J]. J Korean Ceram Soc,2005,42(6):371-376.
[30]	Achi O K,Okolo N I. The Chemical Composition and Some Physical Properties of a Water-soluble Gum from Prosopis Africana Seeds[J]. Int J Food Sci Technol,2004,39(4):431-436.
[31]	Thuresson K,Nilsson S,Lindman B. Effect of Hydrophobic Modification on Phase Behavior and Rheology in Mixtures of Oppositely Charged Polyelectrolytes[J]. Langmuir,1996,12(2):530-537.
[32]	Pelletier E,Viebke C,Meadows J,et al.A Rheological Study of the Order-disorder Conformational Transition of Xanthan Gum[J]. Biopolymers,2001,59(5):339-346.

Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jing YAO, Ming-Ming DAI. Preparation and Properties of Reclaimed Rubber Based on Passenger Car Tire Tread Powder [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 52-58.
[2]	Bing-Gang CHEN, San-Rong LIU, Zi-Jiang JIANG, Xi-Fei YU. Preparation and Properties Characterization of Hydrophilic Polysiloxane and Polyvinyl Alcohol Composite as Skin Barrier Material [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1224-1236.
[3]	Bing-Bing LENG, Chun-Hui ZHU, Cheng-Ying SHI, Zhi-Peng WANG, Yang LIU, Hong-Yan ZHANG, Wen-Ge XU, Bai-Jun LIU. Preparation and Flame Retardancy of the Irradiation‑crosslinked PE‑based Composites Containing a Cyclophosphazene Derivative [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1672-1679.
[4]	Jing-Wen WANG, Ya-Wen LYU, Ya-Zhuo SHANG, Hong-Lai LIU. Preparation and Properties of Rice Starch Film [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1693-1702.
[5]	LIU Wen-Bin, YANG Sha-Sha, HUANG Guo-Lin, FAN Li-Jiao, XIE Yu-Ming. Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 658-667.
[6]	YANG Yang, CHEN Qi, LI Zhi-Peng, GU Zhuo-Ran, YE Shi-Gui, SHE Xue. Synthesis and Evaluation of High Temperature Resistant Zirconium Boron Crosslinker for Fracturing Fluid [J]. Chinese Journal of Applied Chemistry, 2021, 38(4): 431-438.
[7]	FAN Liangjiao, TIAN Yuqin, QIAN Qin, CHEN Lei, GUO Hongwei, XIN Aiyuan, HOU Wanguo. Rheological Properties of Xanthan Gum/Guar Gum Mixed Solution and Its Borax-Crosslinked System [J]. Chinese Journal of Applied Chemistry, 2020, 37(5): 531-540.
[8]	PAN Ge, LIU Fang, FU Zhilei, LI Shuangshuang, XU Donghua, XU Zhaohua, SHI Tongfei, WANG Xiaowei, MA Rui. Effect of Mass Fraction of Color Paste in Waterborne Polyurethane Coatings on Low Temperature Blasting Properties of Polyvinyl Chloride Skin [J]. Chinese Journal of Applied Chemistry, 2020, 37(2): 182-189.
[9]	WANG Xiaowei, FU Zhilei, LIU Fang, PAN Ge, XU Donghhua, GUAN Dongbo, DOU Yanli, SHI Tongfei, YAO Weiguo. Effect of Polyvinyl Chloride Skin Composition on Vulcanization of Additive Silicone Rubber [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 32-39.
[10]	JI Fance, LIU Xiangdong, SHENG Dekun, YANG Yuming. Photothermal-Induced Shape Memory Polymers Prepared by Reactive Blending [J]. Chinese Journal of Applied Chemistry, 2019, 36(8): 904-908.
[11]	MA Rui,LI Shuangshuang,WANG Xiaowei,FU Zhilei,PAN Ge,FU Bo,SHI Tongfei,HUANG Yineng,TANG Huaqing,LI Sijia,XU Donghua,ZHOU Hengwei. Relationship Between Particle Size and Distribution of Commercial Polyacrylic Superabsorbent Resin and Its Gelation Concentration [J]. Chinese Journal of Applied Chemistry, 2019, 36(7): 807-814.
[12]	Cheng TANG,Zhijuan ZOU,Kunpeng SONG. Preparation of Ni-P Co-doped Hyper-Crosslinked Polymer and Used for Reduction of 4-Nitrophenol [J]. Chinese Journal of Applied Chemistry, 2019, 36(7): 782-789.
[13]	Gang HUANG, Hongwei ZHANG, Huanhuan ZHANG, Tongfei SHI, Donghua XU. Influence of Graphene Oxide on the Rheological Properties of Poly(vinyl alcohol)/Borate Hydrogel [J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 767-775.
[14]	ZHANG Deguang, LI Yanguo, CUI Lei, LI Yuesheng. Controlled Preparation of Crosslinked Isotactic Polypropylene via Diels-Alder Reaction [J]. Chinese Journal of Applied Chemistry, 2018, 35(2): 174-180.
[15]	LU Dali,CHEN Yong,ZHANG Jun,YANG Xue. Synthesis and Properties of Modified Polymer Fracturing Fluid [J]. Chinese Journal of Applied Chemistry, 2018, 35(11): 1295-1300.