Colored Poly(styrene-co-acrylic acid) Nanospheres Prepared by Dyeing with Disperse Dyes

doi:10.11944/j.issn.1000-0518.2015.01.140117

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (1): 64-70.DOI: 10.11944/j.issn.1000-0518.2015.01.140117

• Full Papers • Previous Articles Next Articles

Colored Poly(styrene-co-acrylic acid) Nanospheres Prepared by Dyeing with Disperse Dyes

XIA Xiaojie, FANG Kuanjun^*, REN Bin, CAI Yuqing, ZHANG Jianbo, ZHAO Yunguo, HAO Longyun

The Growing Base for State Key Laboratory of Fiber Materials and Modern Textiles,Qingdao University,Qingdao,Shandong 266071,China

Received:2014-04-08 Revised:2014-06-26 Published:2015-01-06 Online:2015-01-06
Contact: Corresponding author:FANG Kuanjun, professor; Tel/Fax:0532-85956039; E-mail:13808980221@163.com; Research interests:green textile chemistry and new technology of dyeing and finishing
Supported by:
Supported by the National Natural Science Foundation of China(No.51173086), National Key Technology R&D Program(No.2014BAC13B02, No.2014BAE01B01), Industrialization Projects of Major Independent Innovation Achievements of Shandong Province(No.2012ZHZX1A0914)

Abstract

Abstract:

Two disperse dyes were used to color poly(styrene-co-acrylic acid)[P(St-co-AA)] nanospheres at temperatures below the glass transition temperature of the nanoshperes(110.69 ℃). Then we studied the effect of temperature(75~95 ℃) and dye concentration(1%~5%) on the dye content adsorbed on the nanopheres.The results show that the higher the dyeing temperature the more the dye stained on the nanospheres. Increasing the dye concentration of dyeing bath results in higher dye contents on the nanospheres. Higher dye contents gave brighter and deeper colors of the nanospheres. The dye contents of the nanospheres colored with disperse blue 2BLN, which has two amino groups and two hydroxyl groups, are lower than the dye contents of the nanospheres colored with disperse red FB, which has one amino group and one hydroxyl group. After being dyed, the nanospheres become very rough and the size increases 23 nm. The cotton fabrics after cationic modification were dyed with the colored nanospheres. The dyed cotton fabrics obtain deep and bright colors with a very small amount of the colored nanospheres.

Key words: disperse dye, poly(styrene-co-acrylic acid), colored nanosphere, dye content

CLC Number:

O641

XIA Xiaojie, FANG Kuanjun, REN Bin, CAI Yuqing, ZHANG Jianbo, ZHAO Yunguo, HAO Longyun. Colored Poly(styrene-co-acrylic acid) Nanospheres Prepared by Dyeing with Disperse Dyes[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 64-70.

References

[1] Peterson J I. Dye-containing Polymer Composition:US,4194877 [P].1980-05-25.
[2] Reza Arshady. Microspheres for Biomedical Application:Preparation of Reactive and Labeled Microspheres[J]. Biomaterial ,1993,14(1):5-15.
[3] Dong G Y,Jeong H A,Jin Y B, et al . Preparation and Characterization of Acrylic-based Electronic Inks by in Situ Emulsifier-free Emulsion Polymerization for Electrophoretic Displays[J]. Chem Mater ,2004,16(23):4693-4698.
[4] Mohammad S K,Mohammad E Y,Mohammad R N. Effect of Cationization on Adsorption of Silver Nanoparticles on Cotton Surfaces and its Antibacterial Activity[J]. Cellulose ,2009,16(6):1147-1157.
[5] Wang P H,Pan C Y. Polymer metal Composite Particles: Metal Particles on Poly(St- co -MAA) Microspheres[J]. J Appl Polym Sci ,2000,75(14):1693-1698.
[6] Wang P H,Pan C Y. Preparation of Styrene/Methacrylic Acid Copolymer Microspheres and Their Composites with Metal Particles[J]. Colloid Polym Sci ,2000,278(6):581-586.
[7] Wang P H,Pan C Y. Ultrafine Palladium Particles Immobilized on Polymer Microspheres[J]. Colloid Polym Sci ,2001,279(2):171-177.
[8] Wan Ngah W S,Teong L C,Hanafiah M A. Adsorption of Dyes and Heavy Metal Ions by Chitosan Composites:A Review[J]. Carbohydr Polym ,2011,83(4):1446-1456.
[9] Da L,Yuan L,Hou X, et al . Colored Nanoparticles Dispersions as Electronic Inks for Electrophoretic Display[J]. Synth Met ,2011,161(13/14):1270-1275.
[10] Weiss C K,Katharina L. Miniemulsion Polymerization as a Means to Encapsulate Organic and Inorganic Materials[M]. Berlin:Springer-Verlag,2010:185-236.
[11] Ru Q,Zhang X L,Young S K. Synthesis of Functional Microcapsules by in Situ Polymerization for Electrophoretic Image Display Elements[J]. Colloids Surf A : Physicochem Eng Asp ,2008,313/314:347-350.
[12] Liu H,San D. Encapsulation of Pigment Particles by Polymerization:US,7741384 B2[P].2010-06-22.
[13] Solans C,Izquierdo P,Nolla J, et al . Nano-emulsions[J]. Curr Opin Colloid Interface Sci ,2005,10(3/4):102-110.
[14] Yu D G,An J H,Bae J Y, et al . Negatively Charged Ultrafine Black Particles of P(MMA- co -EGDMA) by Dispersion Polymerization for Electrophoretic Displays[J]. Macromolecules ,2005,38(17):7485-7491.
[15] Ibrahim E H,Denizli A,Bektas S. Cadmium Removal from Human Plasma by Cibacron Blue F3GA and Thionein Incorporated into Polymeric Microspheres[J]. J Chromatogr B : Biomed Sci Appl ,1998,720(1/2):217-224.
[16] Takasu M,Kawaguchi H. Preparation of Colored Latex with Polyurea Shell by Miniemulsion Polymerization[J]. Colloid Polym Sci ,2004,283(7):805-811.
[17] Antonietti M, Landfester K. Polyreactions in Miniemulsions[J]. Prog Polym Sci ,2002,27(4):689-757.
[18] Takasu M, Shiroya T,Takeshita K, et al . Improvement of the Storage Stability and Photostability of Colored Latex Prepared by Miniemulsion Polymerization[J]. Colloid Polym Sci ,2003,282(7):740-746.
[19] Takasu M,Shiroya T,Takeshita K, et al . Preparation of Colored Latex Containing Oil-soluble Dyes with High Dye Content by Mini-emulsion Polymerization[J]. Colloid Polym Sci ,2003,282(2):119-126.
[20] Zhao X,Zhou S,Chen M, et al . Effective Encapsulation of Sudan Black B with Polystyrene Using Miniemulsion Polymerization[J]. Colloid Polym Sci ,2009,287:969-977.
[21] Colour Index International,Fourth Edition Online[M/OL]. Society of Dyers and Colourists and the American Association of Textile Chemists and Colorists.
[22] Fang K,Ren B. A Facile Method for Preparing Colored Nanospheres of Poly(styrene- co -acrylic acid)[J]. Dyes Pigm ,2014,(10):50-56.
[23] Deng W,Wang M Y,Chen G, et al . Morphological Evolution of Multistage Polymer Particles in the Alkali Post-treatment[J]. Euro Polym J ,2010,46(6) :1210-1215.
[24] Kim T K,Son Y A,Lim Y J. Thermodynamic Parameters of Disperse Dyeing on Severalpolyester Fibers Having Different Molecular Structures[J]. Dyes Pigm ,2005,67(3):229-234.
[25] Karst D,Nama D,Yang Y. Effect of Disperse Dye Structure on Dye Sorption onto PLA Fiber[J]. J Colloid Interface Sci ,2007,310(1):106-111.

Colored Poly(styrene-co-acrylic acid) Nanospheres Prepared by Dyeing with Disperse Dyes

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Wan-Nian ZHANG, Fang YU, Shan-Lin ZHAO, Zhi-Qiang ZHANG, Yu-Peng HE. Progress in Molecular Dynamics and Hansen Solubility Parameters of Low Molecular Weight Gels [J]. Chinese Journal of Applied Chemistry, 2022, 39(12): 1803-1817.
[2]	Wei-Qiang ZHANG, Chen WANG, Yu-Rong ZHAO, Dong WANG, Ji-Qian WANG, Hai XU. Research Progress of Regulation of Driving Forces in Short Peptide Supramolecular Self‑Assembly [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1190-1201.
[3]	DING Ya-Li, HU Xiang-Xiang, FENG Xuan, ZHANG Ran, SHI Tong-Fei, WEI Lai. Mechanism of Enhancing Antifreeze Protein Activity by Low Molecular Mass Molecules [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1612-1620.
[4]	FANG Xiang-Yu, HU Jun-Jack, WU Fang-Ling, TANG Ke-Qi. Ion Mobility Mass Spectrometry Combined with the Trajectory Method to Determine Gas Phase Ion Structures of Disaccharide-Alkali Metal Ion Adducts [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1655-1662.
[5]	Meng-Wei LI, Hong-Yan WANG, Ying-Ying WANG, Xiao-Ying KANG, Mei-Fang LIU, Yu-Lan CHEN. Supramolecular Self⁃Assembly of Azobenzene⁃4，4'⁃dicarboxylic Acid Derivatives in Water [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1362-1370.
[6]	XIE Zi-Xu, ZHANG Peng-Fei, WANG Xing. Developing New Stereochemistry Antimicrobial Strategy to Advance Biosafety Materials [J]. Chinese Journal of Applied Chemistry, 2021, 38(5): 510-523.
[7]	CAO Ling-Zhi, WANG Zhao-Shuo, WANG Bei. Application of Nano Biomaterials in Antiviral Vaccine Adjuvant [J]. Chinese Journal of Applied Chemistry, 2021, 38(5): 572-581.
[8]	LU Si-Jia, XING Zhuo, YANG Rui-Qin. Detection of Metal Imprints on Non-porous Surfaces [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 116-122.
[9]	QIN Yanfang, QI Yong, HUANG Yuejun, HOU Yingjie, AN Yu, ZHANG Dengke, HAN Yunke, PAN Jigang. Microwave-assisted Synthesis of Cu(Ⅱ)meso-Tetra (Schiff-base substituted phenyl)porphyrins [J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 53-59.
[10]	YANG Yang1*, GAO Chaoying1, XU Liang1, DUAN Limei1, LI Bin2. Progress and Applications of Multi-branched Rhodamine Hydrazone Fluorescent Sensors [J]. Chinese Journal of Applied Chemistry, 2014, 31(10): 1123-1134.
[11]	LV Jianhong1,2, MA Zhihua1, DING Junqiao1, WANG Lixiang1. Synthesis and Characterization of a Green-Emitting Iridium Complex Based on Fluorinated Benzoimidazole Ligand [J]. Chinese Journal of Applied Chemistry, 2014, 31(10): 1177-1184.
[12]	HE Dongqin, FANG Kuanjun*. Studies on the Conductivity of Cationic Latexes and Its Adsorption on Cotton Fabrics by Conductometric Titration [J]. Chinese Journal of Applied Chemistry, 2014, 31(05): 581-588.
[13]	WANG Jianhui, GUO Liqin, RUAN Wenjuan*, ZHU Zhiang. Synthesis and Electrochemical Properties of Salen-type Copper(Ⅱ) and Nickel(Ⅱ) Complexes [J]. Chinese Journal of Applied Chemistry, 2014, 31(03): 303-309.
[14]	XU Rong1, RUAN Lingao2, GE Mei3, ZHANG Yixuan1*. Synthesis of Fluorescein Isothiocyanate-labeled Vancomycin and Its Bacterial Detection by Fluorescence [J]. Chinese Journal of Applied Chemistry, 2014, 31(02): 220-224.
[15]	LIU Daiming, FANG Kuanjun*, CAI Yuqing. Interaction Between Cetyltrimethyl Ammonium Chloride and C.I. Direct Blue 199 [J]. Chinese Journal of Applied Chemistry, 2013, 30(09): 1054-1059.