Microwave-assisted Synthesis of Cu(Ⅱ)meso-Tetra (Schiff-base substituted phenyl)porphyrins

doi:10.11944/j.issn.1000-0518.2015.01.140121

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (1): 53-59.DOI: 10.11944/j.issn.1000-0518.2015.01.140121

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Microwave-assisted Synthesis of Cu(Ⅱ)meso-Tetra (Schiff-base substituted phenyl)porphyrins

QIN Yanfang^a, QI Yong^a, HUANG Yuejun^b, HOU Yingjie^a, AN Yu^a, ZHANG Dengke^a, HAN Yunke^a, PAN Jigang^{a, *}

^aSchool of Chemistry and Chemical Engineering,Shanxi University,Taiyuan 030006,China;
^bShanxi Pharmaceutical College,Taiyuan 030031,China

Received:2014-04-11 Revised:2014-07-08 Published:2015-01-06 Online:2015-01-06
Contact: Corresponding author:PAN Jigang, associate professor; Tel:0351-7010588; E-mail: panjigang_sxu@126.com; Research interests:organic synthesis
Supported by:

Abstract

Abstract:

Cu(Ⅱ)meso-tetra(Schiff-base substituted phenyl)porphyrins were synthesized under microwave heating. The experimental results show that the species of substituents on substituted benzaldehyde affect the condensation reaction rates and yields between benzaldehyde and Cu(Ⅱ)meso-5,10,15,20-tetrakis(4-aminophenyl)porphyrin. Cu complex can be formed between the side-chain of salicylaldehyde-Schiff base copper metalloporphyrin and copper ions in alkaline conditions. The conversion and the selectivity of its catalytic oxidation of cyclohexane to cyclohexanone is up to 7.68% and 60.87%, respevtively.

Key words: Cu(Ⅱ)meso-tetrakis(aminophenyl)porphyrin, Cu(Ⅱ)meso-tetra(Schiff-base substituted phenyl) porphyrins, microwave, Cu complex, catalytic oxidation

CLC Number:

QIN Yanfang, QI Yong, HUANG Yuejun, HOU Yingjie, AN Yu, ZHANG Dengke, HAN Yunke, PAN Jigang. Microwave-assisted Synthesis of Cu(Ⅱ)meso-Tetra (Schiff-base substituted phenyl)porphyrins[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 53-59.

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Microwave-assisted Synthesis of Cu(Ⅱ)meso-Tetra (Schiff-base substituted phenyl)porphyrins

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