咪唑二羧酸构筑的铕配合物的合成、晶体结构及发光性能

doi:10.11944/j.issn.1000-0518.2018.01.170336

摘要/Abstract

摘要：

2-(邻溴)苯基-4,5-咪唑二羧酸(o-BrPhH₃IDC)与六水合硝酸铕(Eu(NO₃)₃·6H₂O)在对苯二甲酸存在下,在乙睛和水的混合溶剂中,通过溶剂热反应,合成了一个三维超分子配合物(H₃O)[Eu(o-BrPhH₂IDC)₄](1)。采用单晶X射线衍射对配合物1的晶体结构进行了测试,结果表明,配合物1为立方晶系,I-43d空间群;中心铕离子处于一个八配位的体系中。对配合物1的固态荧光研究发现:在395 nm的激发波长下,标题配合物显示出特征的铕发射光谱。这说明所采用的有机配体具有良好的天线效应,对铕离子有很好的敏化效应。

关键词: Eu-配合物, 咪唑二羧酸, 晶体结构, 荧光性能

Abstract:

By solvothermal reaction of Eu(NO₃)₃ 6H₂O with 2-(2-bromophenyl)-1H-imidazole-4,5-dicarboxylic acid (o-BrPhH₃IDC) in the presence of terephthalic acid, a three-dimensional supramolecular complex (H₃O)[Eu(o-BrPhH₂IDC)₄](1) was prepared. The crystal structure of complex 1 was determined by single crystal X-ray diffraction. The results show that complex 1 crystallizes in the cubic system, I-43d space group, and the central europium ion is in a eight-coordinate system. The solid-state fluorescence of complex 1 reveals that complex 1 exhibits a characteristic europium emission spectra at the excitation wavelength of 395 nm which implies that the organic ligand has a good antenna effect and a good sensitization effect on europium ion.

Key words: Eu-complex, imidazole dicarboxylate, crystal structure, fluorescence properties

林肖漪, 朱永朝, 孟祥茹. 咪唑二羧酸构筑的铕配合物的合成、晶体结构及发光性能[J]. 应用化学, 2018, 35(1): 82-88.

LIN Xiaoyi, ZHU Yongchao, MENG Xiangru. Synthesis, Crystal Structure and Luminescent Properties of a Europium Complex from Imidazole Dicarboxylate[J]. Chinese Journal of Applied Chemistry, 2018, 35(1): 82-88.

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