基于一维[H2Mo4O14]n2n-链和双吡啶双酰胺配体的三维锌配合物的合成、结构与性能

doi:10.11944/j.issn.1000-0518.2017.06.160307

摘要/Abstract

摘要：

选择柔性的双吡啶双酰胺配体N,N'-双(3-吡啶甲酰胺基)-1,2-乙烷(3-bpye)、钼酸铵和氯化锌在水热条件下自组装制备了一个基于一维[H₂Mo₄O₁₄]_n^2n-链的三维锌配合物[Zn(3-bpye)(H₂Mo₄O₁₄)(H₂O)₂],并通过元素分析、红外光谱、热重分析等技术手段研究了配合物的结构,并利用X射线单晶衍射分析进行了晶体结构表征。结构解析揭示标题配合物是三斜晶系,P-1空间群,晶胞参数a=0.61310(3) nm,b=1.04750(6) nm,c=1.06540(6) nm,α=78.5540(10)°,β=77.5350(10)°,γ=89.9050(10)°,V=0.65420(6) nm³,M_r=981.47,D_c=2.491 g/cm³,Z=1,F(000)=468,R₁=0.0290,ωR₂=0.1068。标题配合物中,金属锌离子连接一维[H₂Mo₄O₁₄]_n^2n-链形成一种二维无机双金属层[Zn(H₂Mo₄O₁₄)]_n,相邻的层间又通过双齿配体3-bpye连接形成三维CdSO₄拓扑的骨架结构。配合物表现出强的荧光发射特性,而且其在紫外光照下对亚甲基蓝和罗丹明B均有明显的催化降解活性。 CCDC:1493115

关键词: 多钼酸盐, 双吡啶双酰胺配体, 锌配合物, 晶体结构, 荧光性质, 光催化活性

Abstract:

A three-dimensional(3D) zinc compound [Zn(3-bpye)(H₂Mo₄O₁₄)(H₂O)₂](3-bpye=N,N'-bis(3-pyridinecarboxamide)-1,2-ethane) based on one-dimensional(1D) [H₂Mo₄O₁₄]_n^2n- chain was hydrothermally prepared by bis(pyridyl)-bis(amide) ligand, ammonium molybdate and zinc chloride. Structural analysis by element analysis, indrared(IR) spectroscopy, thermogravity(TG) and X-ray single-crystal diffraction(XRD) reveal that the title compound is triclinic system with P-1 space group. Its cell parameters are a=0.61310(3) nm, b=1.04750(6) nm, c=1.06540(6) nm, α=78.5540(10)°, β=77.5350(10)°, γ=89.9050(10)°, V=0.65420(6) nm³, M_r=981.47, D_c=2.491 g/cm³, Z=1, F(000)=468, R₁=0.0290, ωR₂=0.1068. In the title compound, 1D [H₂Mo₄O₁₄]_n^2n- chains are linked by the Zn²⁺ ions to form 2D inorganic bimetallic layer [Zn(H₂Mo₄O₁₄)]_n. The adjacent 2D layers are further connected by the bridging ligands 3-bpye to construct 3D framework with CdSO₄ topology. This zinc compound possesses strong fluorescence emission. Moreover, this compound shows remarkable photocatalytic activities for the degradation of methylene blue and rhodamine B under ultraviolet irradiation. CCDC: 1493115.

Key words: polyoxomolybdate, bis(pyridyl)-bis(amide) ligand, zinc compound, crystal structure, fluorescent property, photocatalytic activity

林宏艳, 孙俊俊, 王青林, 曾凌, 刘国成, 林佳凤. 基于一维[H₂Mo₄O₁₄]_n^2n-链和双吡啶双酰胺配体的三维锌配合物的合成、结构与性能[J]. 应用化学, 2017, 34(6): 693-699.

LIN Hongyan, SUN Junjun, WANG Qinglin, ZENG Ling, LIU Guocheng, LIN Jiafeng. A Three-Dimensional Zinc Compound Based on One-Dimensional [H₂Mo₄O₁₄]_n^2n- Chain and Bis(pyridyl)-Bis(amide) Ligand: Synthesis, Structure and Property[J]. Chinese Journal of Applied Chemistry, 2017, 34(6): 693-699.

参考文献

[1]	Guo Z Y,Song X Z,Lei H P,et al. A Ketone Functionalized Luminescent Terbium Metal-Organic Framework for Sensing of Small Molecules[J]. Chem Commun,2015,51(2):376-379.
[2]	Mondloch J E,Karagiaridi O,Farha O K,et al. Activation of Metal Organic Framework Materials[J]. CrystEngComm,2013,15(45):9258-9264.
[3]	Wu P Y,Jiang M,Hu X F,et al. Amide-containing Luminescent Metal Organic Complexes as Bifunctional Materials for Selective Sensing of Amino Acids and Reaction Prompting[J]. RSC Adv,2016,6(33):27944-27951.
[4]	Sha J Q,Sun J W,Zhu ,et al. The First Two-fold Interpenetrating Polyoxometalate-based Coordination Polymer with Helical Channels: Structure and Catalytic Activities[J]. CrystEngComm,2016,18(2):283-289.
[5]	Wang Y,Sun X P,Li S Z,et al. Generation of Large Polynuclear Rare Earth Metal-Containing Organic Inorganic Polytungstoarsenate Aggregates[J]. Cryst Growth Des,2015,15(5):2057-2063.
[6]	Xu S S,Chen W L,Wang Y H,et al. Co-sensitization Promoted Light Harvesting with a New Mixed-addenda Polyoxometalate [Cu(C12H8N2)2]2[V2W4O19]·4H2O in Dye-sensitized Solar Cells[J]. Dalton Trans,2015,44(42):18553-18562.
[7]	Fu H,Qin C,Lu Y,et al. An Ionothermal Synthetic Approach to Porous Polyoxometalate-Based Metal Organic Frameworks[J]. Angew Chem,2012,124(32):8109-8113.
[8]	Lan Y Q,Li S L,Wang X L,et al. Selfassembly of Polyoxometalate-based Metal Organic Frameworks Based on Octamolybdates and Copper-organic Units:From CuⅡ, CuⅠ,Ⅱ to CuⅠ via Changing Organic Amine[J]. Inorg Chem,2008,47(18):8179-8187.
[9]	Du X D,Li C H,Zhang Y,et al. Coordination Polymers Based on the Octamolybdate and Flexible Bis(triazole) Ligands with Different Spacer Lengths[J]. CrystEngComm,2011,13(7):2350-2357.
[10]	Kan W Q,Yang J,Liu Y Y,et al. Series of Inorganic Organic Hybrid Materials Constructed From Octamolybdates and Metal Organic Frameworks:Syntheses, Structures, and Physical Properties[J]. Inorg Chem,2012,51(21):11266-11278.
[11]	Zhang C J,Pang H J,Tang Q,et al. Tailoring Microstructures of Isopolymolybdates:Regular Tuning of the Ligand Spacer Length and Metal Coordination Preferences[J]. Dalton Trans,2010,39(34):7993-7999.
[12]	Yang M X,Lin S,Chen L J,et al. Two Novel 3D Bimetallic Oxide Framework with 16-Membered Wheel Clusters Based on {Mo5O16} Ribbon-like Chains[J]. Inorg Chem Commun,2011,14:1652-1655.
[13]	Liu H Y,Wu H,Yang J,et al. pH-Dependent Assembly of 1D to 3D Octamolybdate Hybrid Materials Based on a New Flexible Bis-[(pyridyl)-benzimidazole] Ligand[J]. Cryst Growth Des,2011,11(5):2920-2927.
[14]	Chen Y Q,Li G R,Qu Y K,et al. Water-Insoluble Heterometal-Oxide-Based Photocatalysts Effective for the Photo-Decomposition of Methyl Orange[J]. Cryst Growth Des,2013,13(2):901-907.
[15]	Chen H L,Li M X,He X,et al. Seven Organic Inorganic Hybrid Compounds Constructed from 2,4,6-Tris-(pyridyl)-1,3,5-triazine and Polyoxometalates[J]. Inorg Chim Acta,2010,36:3186-3193.
[16]	Lin H Y,Xu C,Wang X L,et al. Chains and the Flexible Bis-pyridyl-bis-amide Ligand[J]. Inorg Chem Commun,2013,36:81-85.
[17]	Wang X L,Sun J J,Lin H Y,et al. Novel Anderson-type [TeMo6O24]6--based Metal-organic Complexes Tuned by Different Species and Their Coordination Modes:Assembly, Various Architectures and Properties[J]. Dalton Trans,2016,45(6):2709-2719.
[18]	Wang X L,Chang Z H,Lin H Y,et al. Effect of Polyoxoanions and Amide Group Coordination Modes on the Assembly of Polyoxometalate-based Metal-organic Complexes Constructed from a Semi-rigid Bis-pyridyl-bis-amide Ligand[J]. CrystEngComm,2015,17(4):895-903.
[19]	Wang X L,Chang Z H,Lin H Y,et al. Assembly and photocatalysis of Two Novel 3D Anderson-type Polyoxometalate-based Metal-organic Frameworks Constructed from Isomeric Bis(pyridylformyl)piperazine Ligands[J]. Dalton Trans,2014,43(32):12272-12278.
[20]	Wang X L,Sun J J,Lin H Y,et al. A series of Anderson-type Polyoxometalate-based Metal-organic Complexes:Their pH-Dependent Electrochemical Behaviour, and as Electrocatalysts and Photocatalysts[J]. Dalton Trans,2016,45(31):12465-12478.
[21]	LIN Hongyan,ZENG Ling,WANG Qinglin,et al. Synthesis, Structure and Catalytic Properties of the Keggin-type Silicomolybdenate-based Silver Compound Modified by a Bis-pyridyl-bis-amide Ligand[J]. Chinese J Appl Chem,2016,33(1):76-83(in Chinese). 林宏艳,曾凌,王青林,等. 一种双吡啶双酰胺配体修饰的Keggin型硅钼酸盐基配合物的合成、结构与催化性能[J]. 应用化学,2016,33(1):76-83.
[22]	Muthu S,Yip J H K,Vittal J J,et al. Coordination Networks of Ag(Ⅰ) and N,N'- Bis(3-pyridinecarboxamide)-1,6-hexane:Structures and Anion Exchange[J]. J Chem Soc,Dalton Trans,2002,(24):4561-4568.
[23]	Brown I D,Altermatt D. Bond-valence Parameters Obtained from a Systematic Analysis of the Inorganic Crystal Structure Database[J]. Acta Crystallogr,Sect B,1985,41(4):244-247.
[24]	Dong B X,Xu Q. Investigation of Flexible Organic Ligands in the Molybdate System:Delicate Influence of a Peripheral Cluster Environment on the Isopolymolybdate Frameworks[J]. Inorg Chem,2009,48(13):5861-5873.
[25]	Adarsh N N,Dastidar P. A New Series of ZnⅡ Coordination Polymer Based Metallogels Derived from Bis-pyridyl-bis-amide Ligands:A Crystal Engineering Approach[J]. Cryst Growth Des,2011,11(1):328-336.
[26]	Dutta D,Jana A D,Debnath M,et al. Robust 1D Open Rack-like Architecture in Coordination Polymers of Anderson POMs [{Na4(H2O)14}{Cu(gly)}2][TeMo6O24] and [{Cu(en)2}3{TeW6O24}]:Synthesis, Characterization and Heterogeneous Catalytic Epoxidation of Olefines[J]. Dalton Trans,2010,39(48):11551-11559.
[27]	Xu C Y,Li L K,Wang Y P,et al. Three-dimensional Cd(Ⅱ) Coordination Polymers Based on Semirigid Bis(methylbenzimidazole) and Aromatic Polycarboxylates:Syntheses, Topological Structures and Photoluminescent Properties[J]. Cryst Growth Des,2011,11(10):4667-4675.
[28]	Li S B,Zhang L,O'Halloran K P,et al. An Unprecedented 3D POM-MOF Based on (7,8)-Connected Twin Wells-Dawson Clusters:Synthesis, Structure, Electrocatalytic and Photocatalytic Properties[J]. Dalton Trans,2015,44(6):2062-2065.
[29]	Wang X L,Han N,Lin H Y,et al. pH and Amine-induced Various Octamolybdate-based Metal-organic Complexes:Assembly, Structures and Properties[J]. Dalton Trans,2014,43(5):2052-2060.

基于一维[H₂Mo₄O₁₄]_n^2n-链和双吡啶双酰胺配体的三维锌配合物的合成、结构与性能

A Three-Dimensional Zinc Compound Based on One-Dimensional [H₂Mo₄O₁₄]_n^2n- Chain and Bis(pyridyl)-Bis(amide) Ligand: Synthesis, Structure and Property

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	杜志鹏, 周洋, 赵三根. 银簇化合物Ag₃B₆O₁₀I的合成、晶体结构和双折射性质[J]. 应用化学, 2023, 40(2): 229-235.
[2]	刘进剑, 刘娜, 杨凤意. 2种同构紫精配位聚合物的合成及其光致变色性能[J]. 应用化学, 2023, 40(2): 245-251.
[3]	唐静, 林肖漪, 周文艳, 黄秋颖. 一维发光镉配位聚合物的合成、晶体结构及识别性能[J]. 应用化学, 2019, 36(4): 459-464.
[4]	张斌,孙雪娇,吕成伟,于世钧. 含8-羟基喹啉侧基聚酯及其锌和铝配合物的合成与荧光性质[J]. 应用化学, 2019, 36(3): 306-313.
[5]	朱晴雯, 余浩田, 刘梦琴, 张复兴, 邝代治, 谭宇星, 蒋伍玖. 基于酰腙配体的双锡核二(2,4-二氯苄基)锡配合物的合成、结构及生物活性[J]. 应用化学, 2019, 36(12): 1387-1396.
[6]	杨春林, 冯泳兰, 张复兴, 庾江喜, 蒋伍玖, 邝代治. 双(取代水杨醛)缩卡巴肼正丁基锡配合物的合成、结构及除草活性[J]. 应用化学, 2018, 35(7): 795-801.
[7]	孙英华, 杨美玲, 梅泽民. 一种新型钼钒多酸化合物的合成、结构与荧光性能[J]. 应用化学, 2018, 35(5): 589-593.
[8]	张连生, 唐豫媛, 王萃娟, 熊霄阳, 李泽贤, 陈志斌. 2,2'-联苯二羧酸配合物的合成、表征及性质[J]. 应用化学, 2018, 35(4): 442-448.
[9]	顾芷萌,王颖,赵敏,郝秋华,尚迪,白凤英,邢永恒. 三嗪-吡唑钌配合物的合成、结构及光催化活性[J]. 应用化学, 2018, 35(2): 206-215.
[10]	屈小芳,曹亚萍,吴庆,胡庆红,袁泽利. 含氮芥双-(亚苄基)环烷酮的合成、晶体结构及其体外光动力抗肿瘤活性[J]. 应用化学, 2018, 35(11): 1317-1324.
[11]	林宏艳,田原,王青林,曾凌,刘国成,赵延玉. 基于一维双螺旋链的锌配合物的合成与荧光性能[J]. 应用化学, 2018, 35(11): 1372-1377.
[12]	王玉, 张莉静, 王颖, 白凤英, 邢永恒. 吡唑-吡啶铕配合物的合成、结构及荧光效应[J]. 应用化学, 2018, 35(10): 1256-1263.
[13]	林肖漪, 朱永朝, 孟祥茹. 咪唑二羧酸构筑的铕配合物的合成、晶体结构及发光性能[J]. 应用化学, 2018, 35(1): 82-88.
[14]	黄秋颖, 林肖漪, 王勇, 朱永朝. 波浪形一维链状镉配合物的合成、结构及分子识别性能[J]. 应用化学, 2017, 34(9): 1093-1098.
[15]	李建法, 陈小莉. 双核锌配合物[Zn(dna)(phen)(H₂O)]的合成、结构及性质[J]. 应用化学, 2017, 34(8): 912-917.