换热器与相变材料的兼容性研究进展

doi:10.11944/j.issn.1000-0518.2016.12.160102

摘要/Abstract

摘要：

相变材料是一类以潜热实现能量存储释放的储能材料,由于其在相变温度附近具有很大的储热密度,相变材料可以被用于建筑控温、太阳能热发电和高温传热蓄热等应用中。换热器是相变储能设备的重要组成部分,可以将热量在供需两端进行传递和转移,保障需求一方的使用,随着相变材料研究的不断深入及其工程应用的广泛普及,换热器已在众多相变储能项目中发挥了重要的枢纽作用。为了保证换热器的使用性能,需要对换热器在相变材料中的防腐蚀性进行全面的分析。本文总结了大量国内外的文献,分析不同成分的相变材料对换热器材料的腐蚀性,为换热器材料的选择提供了参考。

关键词: 换热器, 相变材料, 兼容性

Abstract:

Phase change materials(PCM) are used for thermal energy storage through the large energy released and received during phase change. Owing to the high energy density, PCM can be utilized in building thermal comforting, concentrated solar power and thermal transport and conversion at high temperature. Heat exchangers are used to transfer thermal energy between fluids and play a crucial role in enhancing energy efficiency of thermal energy storage devices which employ phase change materials as the storage unit. To guarantee the performance stability and usage safety, the compatibility between heat exchangers and phase change materials are extensively investigated. Herein, we give a comprehensive literature review on this topic. The presented overall study can be a reference for heat exchanger material selection.

Key words: heat exchanger, phase change material, compatibility

金翼,黄心宇,吴文昊,宋鹏翔,杨岑玉,姚锐敏,邹如强. 换热器与相变材料的兼容性研究进展[J]. 应用化学, 2016, 33(12): 1366-1374.

JIN Yi,HUANG Xinyu,WU Wenhao,SONG Pengxiang,YANG Cenyu,YAO Ruimin,ZOU Ruqiang. Research Progress on Compatibility of Heat Exchanger and Phase Change Materials[J]. Chinese Journal of Applied Chemistry, 2016, 33(12): 1366-1374.

参考文献

[1]	Nejat P,Jomehzadeh F,Taheri M M,et al. A Global Review of Energy Consumption, CO2 Emissions and Policy in the Residential Sector(with an Overview of the Top Ten CO2 Emitting Countries)[J]. Renew Sust Energ Rev,2015,43:843-862.
[2]	Liu C,Li F,Ma L P,et al. Advanced Materials for Energy Storage[J]. Adv Energy Mater,2010,22(8):28-62.
[3]	Xu J,Wang R Z,Li Y. A Review of Available Technologies for Seasonal Thermal Energy Storage[J]. Sol Energy,2014,103:610-638.
[4]	Li C,Wang R Z. Building Integrated Energy Storage Opportunities in China[J]. Renew Sust Energ Rev,2012,16(8):6191-6211.
[5]	Kousksou T,Bruel P,Jamil A,et al. Energy Storage:Applications and Challenges[J]. Sol Energy Mater Sol Cells,2014,120:59-80.
[6]	Singh S P,Bhat V. Applications of Organic Phase Change Materials for Thermal Comfort in Buildings[J]. Rev Chem Eng,2014,30(5):521-538.
[7]	Browne M C,Norton B, McCormack S J. Phase Change Materials for Photovoltaic Thermal Management[J]. Renew Sust Energ Rev,2015,47:762-782.
[8]	Li Q,Flamant G,Yuan X,et al. Compact Heat Exchangers:A Review and Future Applications for a New Generation of High Temperature Solar Receivers[J]. Renew Sust Energ Rev,2011,15(9):4855-4875.
[9]	Mohammed H A,Bhaskaran G,Shuaib N H,et al. Heat Transfer and Fluid Flow Characteristics in Microchannels Heat Exchanger Using Nanofluids: A Review[J]. Renew Sust Energ Rev,2011,15(3):1502-1512.
[10]	Bhutta M M A,Hayat N,Bashir M H,et al. CFD Applications in Various Heat Exchangers Design:A Review[J]. Appl Therm Eng,2012,32:1-12.
[11]	Shukla R,Sumathy K,Erickson P,et al. Recent Advances in the Solar Water Heating Systems:A Review[J]. Renew Sust Energy Rev,2013,19:173-190.
[12]	Ho C K,Iverson B D. Review of High-temperature Central Receiver Designs for Concentrating Solar Power[J]. Renew Sust Energy Rev,2014,29:835-846.
[13]	Abhat A. Low-Temperature Latent-Heat Thermal-Energy Storage-Heat-Storage Materials[J]. Sol Energy,1983,30(4):313-332.
[14]	CHEN Xiao,ZHANG Renyuan,LI Feng,et al. Fabrication and Research of Protective Coating for Energy Storage Container in Solar Thermal Power Generation[J]. Mater Rev,2009,23(8):48-50(in Chinese). 陈枭,张仁元,李风,等. 太阳能热发电中储能容器防护涂层的制备与研究[J]. 材料导报,2009,23(8):48-50.
[15]	Ryo Fukahori,Takahiro Nomura,Chunyu Zhu,et al. Thermal Analysis of Al-Si Alloys as High-temperature Phase-change Matieral and Their Corrosion Properties with Ceramic Materials[J]. Appl Energ,2016,163:1-8.
[16]	WEN Hongyan,FAN Xiaoming,LEI Chang. Compatibility between the Molten Mg-15Ca-15Zn Thermal Energy Storage Alloy and Steel Vessel Shell Materials for Phase-transformation Thermal Storage Facility[J]. Spec Cast Nonferrous Alloys,2015,35(6):569-571(in Chinese). 文红艳,范晓明,雷昶. 储热合金Mg-15Ca-15Zn与钢质容器的相容性[J]. 特种铸造及有色金属,2015,35(6):569-571.
[17]	LI Yuanyuan,CHENG Xiaomin. Review on the Low Melting Point Alloys for Thermal Energy Storage and Heat Transfer Applications[J]. Energ Storage Sci and Technol,2013,2(3):189-198(in Chinese). 李元元,程晓敏. 低熔点合金传热储热材料的研究与应用[J]. 储能科学与技术,2013,2(3):189-198.
[18]	DING Jing,Wei Xiaolan,Peng Qiang,et al.Mid- and High-temperature Heat Transfer and Thermal Energy Storage Materials[M]. Beijing:Science Press,2013:161-165(in Chinese). 丁静,魏小兰,彭强,等. 中高温传热蓄热材料[M]. 北京:科学出版社,2013:161-165.
[19]	Heine D. Corrosion Behavior of Steels in Contact with Salt Eutectics as Latent-Heat Storage Materials[J]. Heat Recovery Systems & CHP,1987,7(4):389-394.
[20]	ZHU Jiankun. System Design and Experimental Research on Molten Salt Heat Transfer and Thermal Storage for Concentrating Solar Utilization[D]. Beijing:Beijing University Technology,2006(in Chinese). 朱建坤. 太阳能高温熔盐传热蓄热系统设计及实验研究[D]. 北京:北京工业大学,2006.
[21]	SUN Liping. Experimental Research on Molten Salt Corrosion Property and Optimization[D]. Beijing:Beijing University Technology,2007(in Chinese). 孙李平. 太阳能高温熔盐优选及腐蚀特性实验研究[D]. 北京:北京工业大学,2007.
[22]	Heidenreich G R,Parekh M B. Thermal Energy Storage for Organic Rankine Cycle Solar Dynamic Space Power Systems[C]. 21st Intersociety Energy Conversion Engineering Conference:Advancing Toward Technology Breakout in Energy Conversion,1986,2:791-797.
[23]	LIAO Min. Preparation and Its Performance for High Temperature Molten Carbonate Salts Materials[D]. Guangzhou:South China University of Technology,2009(in Chinese). 廖敏. 高温碳酸熔融盐材料的制备和性能研究[D]. 广州:华南理工大学,2009.
[24]	LIAO Min,DING Jing,WEI Xiaolan,et al. Preparation and Heat Transfer and Thermal Storage Property of High-temperature Carbonate Molten Salt[J]. Inorg Chem Ind,2008,40(10):15-17(in Chinese). 廖敏,丁静,魏小兰,等. 高温碳酸熔盐的制备及传热蓄热性质[J]. 无机盐工业,2008,40(10):15-17.
[25]	LIAO Min,WEI Xiaolan,DING Jing,et al. Thermophysical Property Study of Carbonate Molten Salt LNK[J]. Acta Energ Sol Sin,2010,31(7):863-867(in Chinese). 廖敏,魏小兰,丁静,等. LNK碳酸熔盐热物性能研究[J]. 太阳能学报,2010,31(7):863-867.
[26]	Singh I B,Sen U. The Effect of Nacl Addition on the Corrosion of Mild-Steel in Nano3 Melt[J]. Corros Sci,1993,34(10):1733-1742.
[27]	Guillot S,Faik A,Rakhmatullin A,et al. Corrosion Effects Between Molten Salts and Thermal Storage Material for Concentrated Solar Power Plants[J]. Appl Energy,2012,94:174-181.
[28]	Werner R. Compatibility of Organic Latent-Heat Storage Materials and Plastic Container Materials[J]. Heat Recovery Syst CHP,1987,7(4):383-388.
[29]	Lázaro A,Zalba B,Bobi M,et al. Experimental Study on Phase Change Materials and Plastics Compatibility[J]. AIChE J,2006,52(2):804-808.
[30]	Castell n C,Martorell I,Cabeza L F,et al. Compatibility of Plastic with Phase Change Materials(PCM)[J]. Int J Energy Res,2011,35(9):765-771.
[31]	Ferrer G,Sol A,Barreneche C,et al. Corrosion of Metal Containers for Use in PCM Energy Storage[J]. Renew Energy,2015,76:465-469.
[32]	Sari A,Kaygusuz K. Some Fatty Acids Used for Latent Heat Storage:Thermal Stability and Corrosion of Metals with Respect to Thermal Cycling[J]. Renew Energy,2003,28:939-948.
[33]	Oró E,Miró L,Barreneche C,et al. Corrosion of Metal and Polymer Containers for Use in PCM Cold Storage[J]. Appl Energy,2013,109:449-453.
[34]	Porisini F C. Salt Hydrates Used for Latent-Heat Storage-Corrosion of Metals and Reliability of Thermal Performance[J]. Sol Energy,1988,41(2):193-197.
[35]	Nagano K,Ogawa K,Mochida T,et al. Performance of Heat Charge/Discharge of Magnesium Nitrate Hexahydrate and Magnesium Chloride Hexahydrate Mixture to a Single Vertical Tube for a Latent Heat Storage System[J]. Appl Therm Eng,2004,24(2/3):209-220.
[36]	García-Romero A,Delgado A,Urresti A,et al. Corrosion Behaviour of Several Aluminium Alloys in Contact with a Thermal Storage Phase Change Material Based on Glauber's Salt[J]. Corros Sci,2009,51(6):1263-1272.
[37]	Joseph R D. Corrosion of Aluminum and Aluminum Alloys[M]. Cleveland:ASM International,1999:75-83.
[38]	Farrell A J,Norton B,Kennedy D M. Corrosive Effects of Salt Hydrate Phase Change Materials Used with Aluminium and Copper[J]. J Mater Process Tech,2006,175(1/2/3):198-205.
[39]	Cabeza L F,Illa J,Roca J,et al. Middle Term Immersion Corrosion Tests on Metal-salt Hydrate Pairs Used for Latent Heat Storage in the 32 to 36 Degrees C Temperature Range[J]. Mater Corros,2001,52(10):748-754.
[40]	Cabeza L F,Illa J,Roca J,et al. Immersion Corrosion Tests on Metal-salt Hydrate Pairs Used for Latent Heat Storage in the 32 to 36 Degrees C Temperature Range[J]. Mater Corros,2001,52(2):140-146.
[41]	Cabeza L F,Roca J,Nogues M,et al. Immersion Corrosion Tests on Metal-salt Hydrate Pairs Used for Latent Heat Storage in the 48 to 58 Degrees C Temperature Range[J]. Mater Corros,2002,53(12):902-907.
[42]	Cabeza L F,Roca J,Nogues M,et al. Long Term Immersion Corrosion Tests on Metal-PCM Pairs Used for Latent Heat Storage in the 24 to 29 C Temperature Range[J]. Mater Corros,2005,56(1):33-39.
[43]	Moreno P,Miró L,Solé A,et al. Corrosion of Metal and Metal Alloy Containers in Contact with Phase Change Materials(PCM) for Potential Heating and Cooling Applications[J]. Appl Energy,2014,125:238-245.
[44]	Lv Y J,Zhou W B,Yang Z J,et al. Characteration and Numerical Simulation on Heat Transfer Performance of Inorganic Phase Change Thermal Storage Devices[J]. Appl Therm Eng,2016,93:788-796.
[45]	SHENG Qiang,XING Yuming,LUO Heng. Experiment on Thermal Storage Performance of Barium Hydroxide Octahydrate Phase Change Material[J]. J Beijing Univ Aeronaut Astronaut,2014,40(5):635-638(in Chinese). 盛强,邢玉明,罗恒. 八水氢氧化钡相变材料储热性能实验[J]. 北京航空航天大学学报,2014,40(5):635-638.