1-(芘-1-基)-3-(4-甲氧基苯基)丙烯酮的合成及三阶非线性光学性质

doi:10.11944/j.issn.1000-0518.2016.02.150216

摘要/Abstract

摘要：

合成了一种新的有机非线性光学(NLO)材料1-(芘-1-基)-3-(4-甲氧基苯基)丙烯酮(PMPAK),通过¹H NMR、IR、HR-MS和元素分析表征其结构。以Nd:YAG-Laser System作为光源,激光波长450 nm,脉冲宽度4 ns(FWHM),采用4f相位相干成像技术测定了PMPAK的三阶NLO性质并确定了相关参数:非线性折射率n₂=-1.84×10^-16 m²/W,非线性吸收系数β=2.53×10^-9 m/W,非线性极化率χ⁽³⁾=1.137×10^-10 esu。

关键词: 芘衍生物, (芘基)-(甲氧基苯基)丙烯酮, 查尔酮, 合成, 非线性光学性质

Abstract:

A new nonlinear optical(NLO) organic material 1-(pyrene-1-yl)-3-(4-methoxyphenyl)acrylic ketone(PMPAK) was synthesized and characterized with ¹H NMR, IR, HR-MS and elemental analysis. The three order NLO properties of PMPAK was tested by 4f phase-coherent imaging system which utilized Nd:YAG-Laser System as the light source. The laser pulse was set at the wavelength of 450 nm with the pulse duration of 4 ns(FWHM), thus the relevant parameters were determined as: the nonlinear refractive index n₂=-1.84×10^-16 m²/W, the nonlinear absorption coefficient β=2.53×10^-9 m/W and the third-order nonlinear polarizability χ⁽³⁾=1.137×10^-10 esu.

Key words: pyrene derivatives, Chalcone, (pyrene-yl)-(methoxyphenyl)acrylic ketone, synthesis, nonlinear optical properties

石玉芳, 孙金鱼, 刘成琪, 赵明根. 1-(芘-1-基)-3-(4-甲氧基苯基)丙烯酮的合成及三阶非线性光学性质[J]. 应用化学, 2016, 33(2): 149-154.

SHI Yufang, SUN Jinyu, LIU Chengqi, ZHAO Minggen. Synthesis and Third-order Nonlinear Optical Property of 1-(Pyrene-1-yl)-3-(4-methoxyphenyl)acrylic Ketone[J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 149-154.

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