中华医学超声杂志

应用化学 ›› 1998, Vol. 0 ›› Issue (5): 28-30.

• 研究论文 • 上一篇    下一篇

电荷传输剂TPD的合成及其在电致发光中的应用

钟家伟1, 黄颂羽2, 阴其俊2   

  1. 1. 华东理工大学精细化工系 上海200237;
    2. 华东理工大学物理系 上海200237
  • 收稿日期:1997-12-29 修回日期:1998-04-27 出版日期:1998-10-10 发布日期:1998-10-10
  • 基金资助:
    国家自然科学基金

Synthesis of Charge Transfer Agent TPD and Its Application in Electroluminescence

Zhong Jiawei1, Huang Songyu2, Yin Qijun2   

  1. 1. Department of Fine Chemicals Technology, East China University of Science and Technology, Shanghai 200237;
    2. Department of Physics, East China University of Science and Technology, Shanghai 200237
  • Received:1997-12-29 Revised:1998-04-27 Published:1998-10-10 Online:1998-10-10

PDF

447

被引次数

6 | 2

摘要： 用18-冠-6作相转移催化剂,邻二氯苯作溶剂由二苯基联苯胺与不同取代基的碘苯经乌尔曼反应,制得N,N'-二苯基-N,N'-二取代苯基联苯胺(三苯基二胺)衍生物(简称TPD),并经IR、NMR等表征；作为电荷传输剂,TPD的加入可改善电致发光器件的发光性能。

关键词: 取代三苯基二胺, 合成, 乌尔曼反应, 电致发光性能

Abstract: Three triphenyldiamine derivatives(TPDs) were synthesized by Ullmann reaction of N,N'-diphenyl benzidine with p-CH3, p-OCH3, m-CH3 iodobenzenes, respectively, using 18C6 as phase transfer catalyst and o dichlorobenzene as solvent. Their structures have been verified by IR and NMR maesurements. As a charge transfer agent, addition of TPD improves the luminescent property of the electroluminescent devices.

Key words: substituted triphenyldiamine, synthesis, Ullmann reaction, electroluminescent property

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