应用化学 ›› 1998, Vol. 0 ›› Issue (5): 10-13.

• 研究论文 • 上一篇    下一篇

新型多臂方酸菁化合物的合成及光谱性质

杨成, 袁德其, 杜国华, 曾鸿鸣, 谢如刚   

  1. 四川大学化学系 成都610064
  • 收稿日期:1997-12-25 修回日期:1998-04-27 出版日期:1998-10-10 发布日期:1998-10-10

Synthesis and Spectral Property of Multiarm squaraines

Yang Cheng, Yuan Deqi, Du Guohua, Zeng Hongming, Xie Rugang   

  1. Department of Chemistry, Sichuan University, Chengdu 610064
  • Received:1997-12-25 Revised:1998-04-27 Published:1998-10-10 Online:1998-10-10

摘要: 合成了引入多甘醇醚链的5-N,N-双(2-羟乙基)胺基-1,3-间苯二酚及其衍生物,使之与方酸发生缩合反应,获得了7种新型多臂方酸菁化合物,研究了它们的光谱性质.

关键词: 多臂方酸菁化合物, 合成, 光谱性质

Abstract: 5-N,N-Bis(2-hydroxyethyl)amino-1,3-benzenediol(1a) and its analogs 1b~1g have been synthesized. By condensation of squaric acid with 1a~1g, a class of novel multiarm squaraines, namely-1,3-bis[4-N,N-bis(2-hydroxyethyl)amino-2,6-dihydroxyl phenyl] squaraine(2a) and its analogs(2b~2g) were obtained. The compounds were designed to improve the donor-acceptor-donor charge transfer(D-A-D CT) of squaraines. The spectra properties of the compounds have been discussed.

Key words: multiarm-squaraine, synthesis, spectral property