应用化学 ›› 1996, Vol. 0 ›› Issue (3): 115-116.

• 研究简报 • 上一篇    下一篇

用常压乙炔法合成10-乙烯基吩噻嗪

李笃信, 薄改梅, 张艳春   

  1. 山西大学化学系 太原 030006
  • 收稿日期:1995-09-26 修回日期:1995-12-18 出版日期:1996-06-10 发布日期:1996-06-10

Synthesis of 10-Vinylphenothiazine with Acetylene Under Ordinary Pressure

Li Duxin, Bo Gaimei, Zhang Yanchun   

  1. Department of Chemistry, Shanxi University, Taiyuan 030006
  • Received:1995-09-26 Revised:1995-12-18 Published:1996-06-10 Online:1996-06-10

摘要: 吩噻嗪的衍生物作为有机光电导材料已在电照相方面得到实际应用,作为机能分离型感光体的载流子传输材料具有感光度高、残留电位低等优点.乙烯基吩噻嗪的聚合物不仅具有光电导性能,而且还可以用作橡胶材料的热稳定剂,具有广阔的应用前景.

关键词: 吩噻嗪, 合成, 光电导体

Abstract: A new synthetic method of 10-vinylphenothiazine with C2H2 under ordinary pres-sure was reported.A mixture of phenothiazine and KOH in DMSO was treated with C2H2 at 170℃ for 10 h to give 97% of yield.The reaction mechanism was explored preliminarily.

Key words: vinylphenothiazine, synthesis, photoconductor