中华医学超声杂志

应用化学 ›› 1994, Vol. 0 ›› Issue (5): 110-111.

• 研究论文 • 上一篇    下一篇

2,5,7,9－四硝基－2,5,7,9－四氮杂双环[4.3.0]壬－8－酮的合成

陆明, 魏运洋, 吕春绪, 李兵   

  1. 南京理工大学化工学院 南京 210014
  • 收稿日期:1993-11-15 修回日期:1994-05-03 出版日期:1994-10-10 发布日期:1994-10-10

Synthesis of 2,5,7,9-Tetranitro -2,5,7,9-tetrazabicyclo[4.3.0]nonan-8-one

Lu Ming, Wei Yunyang, L? Chunxu, Li Bing   

  1. Chemical Engineering School, Nanjing University of Science and Technology, Nanjing 210014
  • Received:1993-11-15 Revised:1994-05-03 Published:1994-10-10 Online:1994-10-10

PDF

479

被引次数

5

摘要： 以乙二胺、乙二醛和脲为原料,通过曼尼希反应,合成了2,5,7,9-四氮杂双环[4.3,0]壬-8-酮盐酸盐(Ⅰ).化合物Ⅰ在硝酸-乙酸酐体系中硝化,制得了标题化合物。

关键词: 氮杂环, 环硝胺, 炸药, 合成

Abstract: The synthesis of 2,5,7,9-tetrazabicyclo[4.3.0]nonan-8-one hydrochloride(Ⅰ) from ethylenediamine, glyoxal and urea by Mannich reaction is reported. Nitration of the compound(Ⅰ) with nitric acid in acetic anhydride gave the title compound.

Key words: azacycle, cyclonitramine, explosive, synthesis

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