中华医学超声杂志

应用化学 ›› 1994, Vol. 0 ›› Issue (2): 35-39.

• 研究论文 • 上一篇    下一篇

过渡金属与二取代冠醚固态配合物的制备

卢爱茹1, 张有明1, 张联祥1, 戴玉杰2   

  1. 1. 西北师范大学化学系 兰州 730070;
    2. 河北医学院药学系 石家庄
  • 收稿日期:1993-06-26 修回日期:1993-12-03 出版日期:1994-04-10 发布日期:1994-04-10

Synthesis of Solid Complexes of Disubstituted Benzo Crown Ethers with Transition Metals

Lu Airu1, Zhang Youming1, Zhang Lianxiang1, Dai Yujie2   

  1. 1. Department of Chemistry, Northwest Normal University, Lanzhou 730070;
    2. Department of Pharmacy, Hebei Medical Institute, Shijiazhuang
  • Received:1993-06-26 Revised:1993-12-03 Published:1994-04-10 Online:1994-04-10

PDF

373

被引次数

3

摘要： 由4',5'-二碘苯并15冠5,4',5'-二溴苯并15冠5,4'-溴-5'-硝基苯并15冠5,四溴二苯并18冠6与过渡全属Mn(Ⅱ)、Co(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)、Ag(Ⅰ)、Cd(Ⅱ)的硝酸盐、高氯酸盐、气化物合成了19个未见报道的固态配合物。用元素分析、红外光谱、摩尔电导和差热-热重分析等表征了它们的组成和性质。

关键词: 过渡金属, 二取代冠醚, 固态配合物, 制备, 性质

Abstract: Ninefeen solid complexes of4',5'-diiodobenzo-15-crown-5,4',5'-dibromobenzo-15-crown-5,4'-bromo-5'-nitrobenzo-15-crown-5,and tetrabromodibenzo-18-crown-6 with nitrates,perchlorates,chlorides of Mn(Ⅱ),Co(Ⅱ),Cu(Ⅱ),Zn(Ⅱ),Ag(Ⅰ),and Cd(Ⅱ) have been synthesized Their compositions and properties have been characterized by elemental analysis, thermal analysis, IR spectra,X-ray diffraction analysis and molar conductance measurements.

Key words: transition metal, disubstituted benzo crown ether, solid complex, synthesis, property

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