中华医学超声杂志

应用化学 ›› 1991, Vol. 0 ›› Issue (5): 21-24.

• 研究论文 • 上一篇    下一篇

2,4-二甲基戊二烯基稀土配合物的合成

蔡小平, 龚立新, 陈文启   

  1. 中国科学院长春应用化学研究所, 长春 130022
  • 收稿日期:1990-05-24 修回日期:1990-09-21 出版日期:1991-10-10 发布日期:1991-10-10
  • 基金资助:
    国家自然科学基金

SYNAHESIS OF 2,4-DIMETHYLPENTADIENYL LANTHANIDE COMPLEXES

Cai Xiaoping, Gong Lixin, Chen Wenqi   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022
  • Received:1990-05-24 Revised:1990-09-21 Published:1991-10-10 Online:1991-10-10

PDF

443

被引次数

2

摘要： 通过元素分析、红外光谱、核磁共振谱、热重分析、晶体结构的测定以及对化合物水解产物的分析。确认合成了下列配合物: 〔η5-2,4-(CH3)2C5H5〕LnCl2·3THF(Ln=Nd,Sm,Gd),〔η5-2,4-(C3H)2C5H5〕2LnCl·THF(Ln=Nd,Sm),〔η5-2,4-(CH3)2C5H5)3Ln(Ln=La,Sm,Gd),(2,4-(CH3)2C5H5=2,4-二甲基戊二烯基。 THF=四氢呋喃.

关键词: 二甲基戊二烯, 稀土配合物, 合成

Abstract: The following complexes were prepared by reaction of anhydrous rare earth trichlorideswith[2,4- (CH3)2C5H5]K and characterized by elmental analysis, IR, NMR, themal analysis,X-ray diffraction analysis as well as chemical analysis of the hydrolysis products: [2,4-(CH3)2C5H5]LnCl2·3THF (Ln = Nd, Sm, Gd), [2,4-(CH3)2C5H5]2LnCl·THF (Ln = Nd, Sm), [2,4- (CH3)2C5H5]3Ln (Ln = La, Sm, Gd),(2,4-(CH3)2C5H5 = 2,4-dimethylpentadienyl; THF = tetrahydrofuran).The complexes are soluble in THF and insoluble in petrolum ether.They are moisture-and air-sensitive.

Key words: dimethylpentadiene, lantanide complexes synthesis

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