应用化学 ›› 1991, Vol. 0 ›› Issue (3): 22-25.

• 研究论文 • 上一篇    下一篇

水杨醛半卡巴腙锰配合物

陈克, 黄知金   

  1. 浙江大学化学系, 杭州 310027
  • 收稿日期:1990-04-24 修回日期:1990-08-20 出版日期:1991-06-10 发布日期:1991-06-10

SALICYLALDEHYDE SEMICARBAZONE MANGANESE COMPLEXES

Chen Ke, Huang Zhijin   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310027
  • Received:1990-04-24 Revised:1990-08-20 Published:1991-06-10 Online:1991-06-10

摘要: 以水杨醛半卡巴腙(H2L)为配体合成了3种新型锰配合物:Mn(HL)2·O.5H2O、Mn(HL)L·1.5MeOH和Mn3L2(O2CMe)4·3H2O,并用元素分析、摩尔电导率、磁化率、红外光谱、紫外可见和ESR谱等对其组成和结构进行了研究和讨论。

关键词: 锰配合物, 水杨醛半卡巴腙, 合成

Abstract: Three novel compexes: Mn(HL)2·0.5H2O, Mn(HL)L·1.5MeOH and Mn3L2(O2CMe)4·3H2O, where H2L = salicylaldehyde semicarbazone, have been synthesized and Characterizedby elemental analyses, molar conductivities,magnetic susceptibilities,thermogravimetric andspectral analyses.The possible structure of the complexes are suggested.

Key words: manganese complex, salicyloldehyde semicarbazone synthesis