应用化学 ›› 1989, Vol. 0 ›› Issue (5): 1-10.

• 综述 •    下一篇

过渡金属簇合物合成化学

徐吉庆   

  1. 吉林大学化学系 长春
  • 收稿日期:1988-09-02 修回日期:1989-04-07 出版日期:1989-10-10 发布日期:1989-10-10

SYNTHETIC CHEMISTRY OF CLUSTER COMPOUNDS OF TRANSITION METALS

Xu Jiqing   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1988-09-02 Revised:1989-04-07 Published:1989-10-10 Online:1989-10-10

摘要:

本文以与催化作用紧密相关的金属羰基簇合物的合成和与化学仿生相关的铁硫和钼铁硫簇合物的合成为例,评述了过渡金属簇合物合成化学的发展概况,给出了金属-金属间键合的两条通则(低氧化态金属间容易成键和同一族元素中重金属具有较大的成键倾向)和三类簇合物的主要合成路线。

关键词: 过渡金属羰基簇, 铁硫簇, 钼铁硫簇, 合成, 评述

Abstract:

The developing aspects of synthetic chemistry of cluster compounds of transition metalsare reviewed. The two general rules on bonding between metal atoms in cluster compoundsand main synthetic routes for three classes of clusters, i.e. metal carbonyl clusters, iron-sulfur clusters and molybdenum-iron-sulfur clusters, are given.

Key words: Transition metal carbonyl cluster, Iron-sulfur-cluster, Molybdenum-iron-sulfur cluster, Synthesis, Review