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全氟辛胺修饰石墨烯复合材料的制备、表征及其疏水性能

李远耀,孔妮,林晶晶,段世鹏,陈伟,田思瑶,王贤保*   

  1. (湖北大学材料科学与工程学院 武汉 430062)
  • 收稿日期:2011-05-10 修回日期:2011-07-15 出版日期:2012-03-10 发布日期:2012-03-10
  • 通讯作者: 王贤保，教授; Tel:027-88662132; Fax:027-88661729; E-mail:wxb@hubu.edu.cn; 研究方向：碳纳米材料的制备、性能及应用研究
  • 基金资助:
    国家自然科学基金（50772031）资助项目，湖北省自然科学基金重点项目（创新群体）（2009CDA021），湖北省教育厅重点项目（D20111002）

Preparation, Characterization and Hydrophobic Properties of Pentadecafluorooctylamine Modified Graphene Composites

LI Yuanyao, KONG Ni, LIN Jingjing, DUAN Shipeng, CHEN Wei, TIAN Siyao, WANG Xianbao*   

  1. (Faculty of Materials Science and Engineering,Hubei University,Wuhan 430062)
  • Received:2011-05-10 Revised:2011-07-15 Published:2012-03-10 Online:2012-03-10

PDF

1700

被引次数

3 | 3

摘要： 通过化学法改性石墨烯，用全氟辛胺(FOA)的胺基与氧化石墨烯（GO）的羧基或烷氧基反应制备了含氟石墨烯复合材料（FOA-RGO），用傅里叶红外光谱、热失重分析、拉曼光谱、高分辨透射电子显微镜（HRTEM）以及原子力显微镜（AFM）对复合材料的结构与形貌进行了表征。 结果表明，FOA已经成功地修饰到石墨烯的边缘。与未修饰的石墨烯相比，水滴在FOA-RGO表面上的接触角从68°提高至118°,显示出良好的疏水性能。

关键词: 石墨烯, 全氟辛胺, 化学修饰, 疏水性

Abstract: Graphene composites have been prepared in this paper through the reaction between the amine group of 1-H,1-H-pentadecafluorooctylamine(FOA) and the carboxyl or alkoxy of graphene oxide(GO). The structures of the resulted composites were characterized by the means of FT-IR infrared spectrum, thermogravimetric analyzer, Raman microscope, high resolution transmission electron microscope, and atomic force microscope. The results indicated that the FOA molecule was linked to the edge of graphene. Meanwhile, the contact angle of the FOA-RGO composites was increased to 118° at room temperature compared with that of RGO(68°).

Key words: Graphene, pentadecafluorooctylamine, chemical modification, hydrophobicity

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