水合肼还原金属的研究进展

doi:10.11944/j.issn.1000-0518.2018.07.170293

摘要/Abstract

摘要：

水合肼还原金属主要用于制备金属纳米颗粒、回收废液中的金属元素以及乏燃料后处理。本文对水合肼作为还原剂的液相还原法制备纳米金属材料、金属离子的回收利用及乏燃料后处理等方面的研究进展作了比较全面的综述,并对液相还原法在酸性和碱性情况下,水合肼还原金属存在的差异及有关的机理、特点、影响因素等进行了分析和总结,以期为该领域研究人员在控制制备金属形状、选择实验条件、金属离子回收尤其是乏燃料处理方面提供参考。

关键词: 水合肼, 催化剂, 配位, 还原, 金属

Abstract:

Hydrazine hydrate reduction of metal is mainly applied in the preparation of metal nanoparticles, recovery of metal ions in spent liquid and nuclear fuel. This article reviews the research progress in recent years on the preparation of nano metal materials, the recovery and reuse of metal ions and the used nuclear fuel by hydrazine hydrate as reducing agent or complexing agent in liquid phase reduction process. In liquid phase reduction, the differences and the related mechanisms, characteristics and influencing factors between acidic and alkaline conditions are analyzed and summarized in the process of hydrazine hydrate reduction of metals. This article gives a reference for future research on this field.

Key words: hydrazine hydrate, catalyst, coordination, reduction, metal

郝帅, 蒋冬梅, 张晓腾, 陈俊畅, 夏良树. 水合肼还原金属的研究进展[J]. 应用化学, 2018, 35(7): 756-766.

Shuai HAO, Dongmei JIANG, Lisheng LIU, Xiaoteng ZHANG, Junchang CHEN, Liangshu XIA. Research Progress on Hydrazine Hydrate Reduction of Metal[J]. Chinese Journal of Applied Chemistry, 2018, 35(7): 756-766.

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