应用化学 ›› 2017, Vol. 34 ›› Issue (8): 936-945.DOI: 10.11944/j.issn.1000-0518.2017.08.170019

• 研究论文 • 上一篇    下一篇

C/Fe-Bi2WO6光催化氧化诺氟沙星废水的效能及其机理

陈世界a,汤晓君a,陈茜a,李英杰a*(),高立娣a,王鹏b   

  1. a齐齐哈尔大学化学与化学工程学院 黑龙江 齐齐哈尔 161006
    b哈尔滨工业大学市政环境工程学院 哈尔滨 150090
  • 收稿日期:2017-01-18 接受日期:2017-05-02 出版日期:2017-07-25 发布日期:2017-07-26
  • 通讯作者: 李英杰
  • 基金资助:
    黑龙江省教育厅基本业务专项理工面上项目(135109209)

Efficiency and Mechanism of Photocatalytic Oxidation of Norfloxacin in Wastewater by C/Fe-Bi2WO6

CHEN Shijiea,TANG Xiaojuna,CHEN Xia,LI Yingjiea*(),GAO Lidia,WANG Pengb   

  1. aCollege of Chemistry and Chemical Engineering,Qiqihar University Qiqihar,Heilongjiang 161006,China
    bSchool of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China
  • Received:2017-01-18 Accepted:2017-05-02 Published:2017-07-25 Online:2017-07-26
  • Contact: LI Yingjie
  • Supported by:
    Supported by Research Business Special Fund of Heilongjiang Provincial Education Department(No.135109209)

摘要:

采用树脂碳化和水热两步法制备C/Fe-Bi2WO6光催化剂,对不同光催化剂光催化降解诺氟沙星溶液的去除效果进行对比研究。 考察了条件因素对诺氟沙星(NOR)溶液在模拟太阳光下光催化氧化降解的影响规律。 结果表明,在实验条件下,NOR光催化氧化降解符合L-H拟一级反应动力学模型,在NOR溶液初始浓度10 mg/L、溶液pH=7.0、催化剂用量0.75 g/L、H2O2浓度为200 mg/L、500 W氙灯照射60 min条件下,NOR完全分解,表观速率常数Kapp为0.0751 min-1。 采用分子荧光光谱法,对C/Fe-Bi2WO6光催化氧化去除NOR体系中羟基自由基生成规律进行研究,并推测了反应机理。 结合LC-MS的分析结果,推测了NOR可能的降解路径和中间产物。

关键词: C/Fe-Bi2WO6, 光催化氧化, 诺氟沙星

Abstract:

The C/Fe-Bi2WO6 photocatalyst was prepared by a two-step method, involving resin carbonization and hydrothermal reaction process. Comparative research on photoactivities of different catalysts was carried out. Influence of condition factors on photocatalytic oxidation degradation of norfloxacin(NOR) solution under simulated sunlight irradiation was investigated. The degrading reaction fits the first-order kinetics well under experimental conditions. After irradiation under a 500 W Xenon lamp for 60 min, NOR completely decomposed with the first order reaction rate constant(Kapp) of 0.0751 min-1 under the conditions that the initial concentration of NOR is 10 mg/L, the C/Fe-Bi2WO6 loading is 0.75 g/L, and the concentration of H2O2 is 200 mg/L at pH 7.0. The OH formation in C/Fe-Bi2WO6 photocatalytic oxidation was studied via molecular fluorescence spectrum, and the possible photocatalytic oxidation mechnasim and the degradation paths and intermediate products of NOR were proposed.

Key words: C/Fe-Bi2WO6, photocatalytic oxidation, norfloxacin